The Hayabusa 2 spacecraft brought back to Earth grains of the carbonaceous asteroid Ryugu. Such grains represent the pristine state of CI chondritic materials and have been preserved from exposure to Earth's atmosphere. Here, we show evidence of the presence of organics trapped within the interlayer space of smectite layers in Ryugu grains. No such organics are found in the Orgueil CI meteorite. We put forward that the organics within the interlayer space of smectite in Orgueil CI meteorite were lost during their oxidation on Earth. Also, we propose that the presence of organics within the interlayers space of smectite might be responsible for the possible NH infrared signature observed in Ryugu particles and potentially to a few large C-type asteroids including Ceres.

Mighei-type carbonaceous chondrites (CM) figure among the most primitive objects in the solar system. Yet, they all have experienced various degrees of aqueous alteration having modified their insoluble organic matter (IOM), in a sequence that remains to be accurately constrained. Here, we exposed the IOM of Paris, the least altered CM available, to hydrothermal conditions at 150 °C for 49 days and compared the experimental residue to the IOM of two altered CMs likely originating from the same parent body as Paris, namely Aguas Zarcas and Mukundpura. The experimental residue shows a chemical and isotopic composition similar to those of Aguas Zarcas and Mukundpura IOMs, confirming that these CMs can be seen as altered counterparts of Paris. The abundance of organic radicals also increases significantly during the experiment. Isotopic hotspots do not seem to have been lost during the experiment, suggesting that the hotspots generally observed within the CM IOMs may date back from pre-accretion era. Of note, the Raman signature of the residue differs from that of the CM IOMs, highlighting the need for further experiments better mimicking asteroidal-like conditions.