A single crystal X-ray diffraction study of the reacts with ButCP to give the dinuclear complex Co,(CO), novel complex Pt(PPh,),(ButCP) indicates that the (ButCP).platinum and its near-normal Pt-P bond length (2.320 A)is discussed in relation to its exceptionally small platinumphosphorus coupling constant lJ(PtP) (62 Hz) ; Co,(CO) phospha-alkyne is co-ordinated in a side-on manner to ____ RECENTLY~ we reported syntheses of a number of novel transition metal complexes of phospha-alkenes, R,C=PR'. N.m.r . spectroscopic studies established that co-ordination 5
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.