Abstract.We describe observations of tropical stratospheric water vapor q that show clear evidence of large-scale

[1] The NASA Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft mission was conducted in February-April 2001 over the NW Pacific (1) to characterize the Asian chemical outflow and relate it quantitatively to its sources and (2) to determine its chemical evolution. It used two aircraft, a DC-8 and a P-3B, operating out of Hong Kong and Yokota Air Force Base (near Tokyo), with secondary sites in Hawaii, Wake Island, Guam, Okinawa, and Midway. The aircraft carried instrumentation for measurements of long-lived greenhouse gases, ozone and its precursors, aerosols and their precursors, related species, and chemical tracers. Five chemical transport models (CTMs) were used for chemical forecasting. Customized bottom-up emission inventories for East Asia were generated prior to the mission to support chemical forecasting and to serve as a priori for evaluation with the aircraft data. Validation flights were conducted for the Measurements Of Pollution In The Troposphere (MOPITT) satellite instrument and revealed little bias (6 ± 2%) in the MOPITT measurements of CO columns. A major event of transpacific Asian pollution was characterized through combined analysis of TRACE-P and MOPITT data. The TRACE-P observations showed that cold fronts sweeping across East Asia and the associated warm conveyor belts (WCBs) are the dominant pathway for Asian outflow to the Pacific in spring. The WCBs lift both anthropogenic and biomass burning (SE Asia) effluents to the free troposphere, resulting in complex chemical signatures. The TRACE-P data are in general consistent with a priori emission inventories, lending confidence in our ability to quantify Asian emissions from socioeconomic data and emission factors. However, the residential combustion source in rural China was found to be much larger than the a priori, and there were also unexplained chemical enhancements (HCN, CH 3 Cl, OCS, alkylnitrates) in Chinese urban plumes. The Asian source of CCl 4 was found to be much higher than government estimates. Measurements of HCN and CH 3 CN indicated a dominant biomass burning source and ocean sink for both gases. Large fractions of sulfate and nitrate were found to be present in dust aerosols. Photochemical activity in the Asian outflow was strongly reduced by aerosol attenuation of UV radiation, with major implications for the concentrations of HO x radicals. New particle formation, apparently from ternary nucleation involving NH 3 , was observed in Chinese urban plumes.

[1] Measurements of Pollution in the Troposphere (MOPITT) is a new remote sensing instrument aboard the Earth Observing System (EOS) ''Terra'' satellite which exploits gas correlation radiometry principles to quantify tropospheric concentrations of carbon monoxide (CO) and methane (CH 4 ). The MOPITT CO retrieval algorithm employs a nonlinear optimal estimation method to iteratively solve for the CO profile which is statistically most consistent with both the satellite-measured radiances and a priori information. The algorithm's theoretical basis is described in terms of the observed radiances and their weighting functions, the a priori information, and the retrieval averaging kernels. Examples of actual CO retrievals over scenes with contrasting pollution conditions are demonstrated, and interpreted in the context of the retrieval averaging kernels and a priori.

[1] In this work absolute values of gravity wave (GW) momentum flux are derived from global temperature measurements by the satellite instruments High Resolution Dynamics Limb Sounder (HIRDLS) and Sounding of the Atmosphere using Broadband Emission Radiometry (SABER). Momentum fluxes in the stratosphere are derived for both instruments and for SABER in the whole mesosphere. The large-scale atmospheric background state is removed by a two-dimensional Fourier decomposition in longitude and time, covering even planetary-scale waves with periods as short as 1-2 days. Therefore, it is possible to provide global distributions of GW momentum flux from observations for the first time in the mesosphere. Seasonal as well as longer-term variations of the global momentum flux distribution are discussed. GWs likely contribute significantly to the equatorward tilt of the polar night jet and to the poleward tilt of the summertime mesospheric jet. Our results suggest that GWs can undergo large latitudinal shifts while propagating upward. In particular, GWs generated by deep convection in the subtropical monsoon regions probably contribute significantly to the mesospheric summertime wind reversal at mid-and high latitudes. Variations in the GW longitudinal distribution caused by those convectively generated GWs are still observed in the mesosphere and could be important for the generation of the quasi two-day wave. Indications for quasi-biennial oscillation (QBO) induced variations of GW momentum flux are found in the subtropics. Also variations at time scales of about one 11-year solar cycle are observed and might indicate a negative correlation between solar flux and GW momentum flux.Citation: Ern, M., P. Preusse, J. C. Gille, C. L. Hepplewhite, M. G. Mlynczak, J. M. Russell III, and M. Riese (2011), Implications for atmospheric dynamics derived from global observations of gravity wave momentum flux in stratosphere and mesosphere,

Abstract. We combine CO column measurements from the MOPITT, AIRS, SCIAMACHY, and TES satellite instruments in a full-year (May 2004-April 2005 global inversion of CO sources at 4 • ×5 • spatial resolution and monthly temporal resolution. The inversion uses the GEOS-Chem chemical transport model (CTM) and its adjoint applied to MO-PITT, AIRS, and SCIAMACHY. Observations from TES, surface sites (NOAA/GMD), and aircraft (MOZAIC) are used for evaluation of the a posteriori solution. Using GEOSChem as a common intercomparison platform shows global consistency between the different satellite datasets and with the in situ data. Differences can be largely explained by different averaging kernels and a priori information. The global CO emission from combustion as constrained in the inversion is 1350 Tg a −1 . This is much higher than current bottomup emission inventories. A large fraction of the correction results from a seasonal underestimate of CO sources at northern mid-latitudes in winter and suggests a larger-thanexpected CO source from vehicle cold starts and residential heating. Implementing this seasonal variation of emissions solves the long-standing problem of models underestimating CO in the northern extratropics in winter-spring. A posCorrespondence to: M. Kopacz (mkopacz@princeton.edu) teriori emissions also indicate a general underestimation of biomass burning in the GFED2 inventory. However, the tropical biomass burning constraints are not quantitatively consistent across the different datasets.

[1] We use an inverse model analysis to compare the top-down constraints on Asian sources of carbon monoxide (CO) in spring 2001 from (1) daily MOPITT satellite observations of CO columns over Asia and the neighboring oceans and (2) aircraft observations of CO concentrations in Asian outflow from the TRACE-P aircraft mission over the northwest Pacific. The inversion uses the maximum a posteriori method (MAP) and the GEOS-CHEM chemical transport model (CTM) as the forward model. Detailed error characterization is presented, including spatial correlation of the model transport error. Nighttime MOPITT observations appear to be biased and are excluded from the inverse analysis. We find that MOPITT and TRACE-P observations are independently consistent in the constraints that they provide on Asian CO sources, with the exception of southeast Asia for which the MOPITT observations support a more modest decrease in emissions than suggested by the aircraft observations. Our analysis indicates that the observations do not allow us to differentiate source types (i.e., anthropogenic versus biomass burning) within a region. MOPITT provides ten pieces of information to constrain the geographical distribution of CO sources, while TRACE-P provides only four. The greater information from MOPITT reflects its ability to observe all outflow and source regions. We conducted a number of sensitivity studies for the inverse model analysis using the MOPITT data. Temporal averaging of the MOPITT data (weekly and beyond) degrades the ability to constrain regional sources. Merging source regions beyond what is appropriate after careful selection of the state vector leads to significant aggregation errors. Calculations for an ensemble of realistic assumptions lead to a range of inverse model solutions that has greater uncertainty than the a posteriori errors for the MAP solution. Our best estimate of total Asian CO sources is 361 Tg yr À1 , over half of which is attributed to east Asia.

[1] High Resolution Dynamics Limb Sounder (HIRDLS) temperature profiles are analyzed to derive global properties of gravity waves. We describe a wavelet analysis technique that determines covarying wave temperature amplitude in adjacent temperature profile pairs, the wave vertical wavelength as a function of height, and the horizontal wave number along the line joining each profile pair. The analysis allows a local estimate of the magnitude of gravity wave momentum flux as a function of geographic location and height on a daily basis. We examine global distributions of these gravity wave properties in the monthly mean and on an individual day, and we also show sample instantaneous wave events observed by HIRDLS. The results are discussed in terms of previous satellite and radiosonde observational analyses and middle atmosphere general circulation model studies that parameterize gravity wave effects on the mean flow. The high vertical and horizontal resolution afforded by the HIRDLS measurements allows the analysis of a wider range of wave vertical and horizontal wavelengths than previous studies and begins to show individual wave events associated with mountains and convection in high detail. Mountain wave observations show clear propagation to altitudes in the mesosphere.

Abstract-Aura, the last of the large Earth Observing System observatories, was launched on July 15, 2004. Aura is designed to make comprehensive stratospheric and tropospheric composition measurements from its four instruments, the High Resolution Dynamics Limb Sounder (HIRDLS), the Microwave Limb Sounder (MLS), the Ozone Monitoring Instrument (OMI), and the Tropospheric Emission Spectrometer (TES). With the exception of HIRDLS, all of the instruments are performing as expected, and HIRDLS will likely be able to deliver most of their planned data products. We summarize the mission, instruments, and synergies in this paper.