Low voltage actuators based on poly(vinylidene fluoride) (PVDF) with 10, 25 and 40 % 1-hexyl-3-methylimidazolium chloride ([C6mim][Cl]) and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C6mim][NTf2]) are prepared by solvent casting in order to evaluate the effect of anion size in the bending properties. Independently of the ionic liquid type and content, its presence leads to the crystallization of PVDF in the phase. The addition of ionic liquid into the polymer matrix decreases significantly its degree of crystallinity and the elastic modulus. It is also confirmed the good miscibility between PVDF and IL, determined by the interaction of the CF2 groups from the PVDF chains with the imidazolium ring in the ionic liquid (IL). The AC conductivity of the composites depends both on the amount of ionic liquid content and anion size. The bending movement of the IL/PVDF composites is correlated to their degree of crystallinity, mechanical properties and ionic conductivity value and the best value of bending response (0.53 %) being found for IL/PVDF composite with 40 wt% of [C6mim][Cl] at an applied voltage of 10 volts square signal.
Actuators based on polymer blends of poly(vinylidene fluoride) (PVDF) with 40 % of different ionic liquids (IL) are prepared by solvent casting. NTf2] were selected in order to evaluate the effect of anion and cation sizes in the bending properties. The microstructure, mechanical and electrical properties of the blend depend on the IL type, which in turn leads to a different bending response. In particular, the mechanical properties are independent on the IL type but the AC conductivity of the composites depend more on the anion type than on the size of the alkyl chain connected to the imidazolium based cation. Thus, the bending response of the IL/PVDF composites is correlated with the anion and cation sizes and a maximum bending response of 0.3 % is
Separator membranes based on poly(vinylidene fluoride), PVDF, poly(vinylidene fluoride-co-trifluoroethylene), PVDF-TrFE, poly(vinylidene fluorideco-hexafluropropylene), PVDF-HFP and poly(vinylidene fluoride-cochlorotrifluoroethylene), PVDF-CTFE were prepared by solvent casting method using N,N-dimethylformamide (DMF) as solvent. In all cases, the same polymer/solvent ratio and solvent evaporation temperature were used. For all membranes, porous microstructure is achieved with a degree of porosity larger than 50%. The β-phase content as well as degree of crystallinity were different for each membrane, which were lower for the co-polymer membranes when compared with PVDF. On the other hand, the observed ionic conductivity values, electrolyte uptake, tortuosity and MacMullin number were similar for all membranes. The electrochemical performance of the separator membranes was evaluated in Li/C-LiFePO4 half-cell configuration showing good cyclability and rate capability for all membranes. Among the all separator membranes, PVDF-TrFE demonstrate the best electrochemical performance, with a discharge capacity value of 87 mAh.g-1 after 50 cycles with a capacity retention of 78 % at 2C. Finally, the correlation between the β-phase content in the membranes and the cycling performance was demonstrated (which was significant at high-C rates): larger β-phase contents, leading higher polarity, facilitates faster lithium ion migration within the separator for similar microstructures.
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