In recent years, the search for solutions for the treatment of water pollution by toxic compounds such as phenols and chlorophenols has been increasing. Phenols and their derivatives are widely used in the manufacture of pesticides, insecticides, paper, and wood preservers, among other things. Chlorophenols are partially biodegradable but not directly photodegradable by sunlight and are extremely toxic—especially 2,4,6-trichlorophenol, which is considered to be potentially carcinogenic. As a viable proposal to be applied in the treatment of water contaminated with 2,4,6-trichlorophenol, this paper presents an application study of the thermally activated Mg/Fe layered double hydroxides as photocatalysts for the mineralization of this contaminant. Activated Mg/Fe layered double hydroxides were characterized by X-ray diffraction, thermal analysis, N2 physisorption, and scanning electron microscopy with X-ray dispersive energy. The results of the photocatalytic degradation of 2,4,6-trichlorophenol in aqueous solution showed good photocatalytic activity, with an efficiency of degradation of up to 93% and mineralization of 82%; degradation values which are higher than that of TiO2-P25, which only reached 18% degradation. The degradation capacity is attributed to the structure of the MgO–MgFe2O4 oxides derived from double laminate hydroxide Mg/Fe. A path of degradation based on a mechanism of superoxide and hollow radicals is proposed.
BACKGROUND: The composite materials ZrO 2 /Zn 5 (OH) 6 (CO 3 ) 2 were prepared in only one step by chemical co-precipitation and thermal hydrolysis of urea. ZrO 2 was added at 5, 8 and 10 mol%. The samples were dried at 80 ∘ C and characterized by adsorption-desorption of N 2 isotherms, X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques, and diffuse reflectance (DRS), UV-visible, Fourier-transform infrared (FTIR) and X-ray photoelectron (XPS) spectroscopies. The materials were assessed in the photodegradation of phenol and polychlorinated phenolic molecules under UV-light irradiation. The possible mechanism was discussed from studies that corroborated or discarded the formation of the species •OH, •O 2 − and h + .RESULTS: The addition of ZrO 2 to Zn 5 (OH) 6 (CO 3 ) 2 resulted in a composite material with high photoactivity. The material containing 8 mol% of ZrO 2 (ZnZr-8.0%) was the sample with the best percentages of photodegradation and mineralization. The photodegradation enhancement was achieved partly by an increment in the specific surface area and principally due to localized states originating in the composite interphase which improved charge transfer. XPS study revealed that the ZrO 2 addition increases the oxygen vacancies which enhanced the organic molecule photodegradation via direct hole attack. CONCLUSION: The ZnZr composite system constitutes an excellent alternative for the photodegradation of persistent organic pollutants due to the low cost, high stability and null toxicity of the support Zn 5 (OH) 6 (CO 3 ) 2 .
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