A liquid chromatographic method for any liquid mixture of the 3 herbicides 2,4-D, MCPP, and dicamba, found in commercial formulations, has been collaboratively studied. Each collaborator received 4 samples, 3 of which were ternary formulations and one a binary formulation of amine salts. Concentrations in the formulations range from 0.02 to 2.32% for dicamba, 0.32 to 21.7% for 2,4-D, and 0.22 to 11.6% for MCPP. A binary solvent system and the use of a specified 25 cm column of RP 10 μm in the reverse phase ion suppression mode will selectively quantitate each herbicide, separating many impurities found in the technical products. Standard deviations in each of 11 columns of results obtained indicate good precision. The method has been adopted official first action.
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