The structural and magnetic properties of the tetragonal 2 : 14 : 1 hard magnetic phase (φ) were investigated in Nd 16 Co 76-x Ru x B 8 alloys. The results indicated that Ru substitution does not harm the formation of φ in Co-rich alloys. An antiferromagnetic Co -Ru coupling is concluded. The cell volume initially decreases with the Ru substitution. The coercivity is enhanced and reaches a maximum at the composition where the saturation magnetization has the lowest value. The Curie temperature as well as the mean magnetic moment decrease with increasing Ru concentration. With the increase of the Ru concentration the unit-cell volume increases. A ferrimagnetic ordering is predicted at higher Ru concentrations.
The Nd 16 Co 76−x Ru x C 7 B system has been investigated to assess the effect of boron-carbon combined addition on the ferromagnetic behavior of these intermetallic compounds. The results indicate that the addition of 1 at.% B favors the formation of the tetragonal magnetic phase 2:14:1 in these alloys. With the increase of the Ru concentration is observed an expansion of the lattice in the basal plane as well as a contraction along the c direction of the tetragonal unit cell. The Curie temperature decreases from 432 K at x = 6 to 421 K for x = 27, whereas the saturation magnetization has a steep decrease. The highest T C value has been verified for the alloy with the largest c parameter, despite its a parameter is the smallest one. In comparison to isotypic borides and pure carbides, a loss of coercivity and remanence is observed.
Nd 16 Co 72−x Ru x C 11 B boro-carbides have been prepared by arc melting and studied by X-ray diffraction and magnetization measurements. X-ray diffraction results confirm that all the prepared alloys possess the tetragonal 2:14:1 (P4 2 /mmm) hard magnetic phase. The observed decrease of the magnetization and Curie temperature indicate the development of antiferromagnetic spin correlations with the increase of the Ru content. The combined addition of B and C is favorable to the formation and stabilization of the tetragonal phase in these compounds. At lower Ru contents the Curie temperature is higher than in the corresponding Co-based boride in spite of larger cell volumes.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.