Various membrane separation processes are being used for seawater desalination and treatment of wastewaters in order to deal with the worldwide water shortage problem. Different types of membranes of distinct morphologies, structures and physico-chemical characteristics are employed. Among the considered membrane technologies, membrane distillation (MD), osmotic distillation (OD) and osmotic membrane distillation (OMD) use porous and hydrophobic membranes for production of distilled water and/or concentration of wastewaters for recovery and recycling of valuable compounds. However, the efficiency of these technologies is hampered by fouling phenomena. This refers to the accumulation of organic/inorganic deposits including biological matter on the membrane surface and/or in the membrane pores. Fouling in MD, OD and OMD differs from that observed in electric and pressure-driven membrane processes such electrodialysis (ED), membrane capacitive deionization (MCD), reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), microfiltration (MF), etc. Other than pore blockage, fouling in MD, OD and OMD increases the risk of membrane pores wetting and reduces therefore the quantity and quality of the produced water or the concentration efficiency of the process. This review deals with the observed fouling phenomena in MD, OD and OMD. It highlights different detected fouling types (organic fouling, inorganic fouling and biofouling), fouling characterization techniques as well as various methods of fouling reduction including pretreatment, membrane modification, membrane cleaning and antiscalants application.
Forward osmosis (FO) is a water treatment/separation technology of emerging interest. Due to its complex nature involving various operating parameters, modeling of this separation process is challenging. A solar thermal and photovoltaic-powered FO pilot plant has been optimized by means of a statistical experimental design and response surface methodology. Predictive models were developed for simulation and optimization of different responses such as the water permeate flux, the reverse solute permeate flux and the FO specific performance index that includes the water and reverse solute permeate fluxes together with the energy consumption. The considered input variables of the FO pilot plant were the feed flow rate, the permeate flow rate and the temperature. The developed response models have been tested using the analysis of variance. A Monte Carlo Simulation method has been conducted to determine the optimum operating conditions of the FO pilot plant. The obtained optimum parameters were confirmed experimentally. Regeneration of the draw solution can be performed by means of an optimized solar powered reverse osmosis (RO) pilot plant with an optimum FO specific performance index ranging from 25.79 to 0.62 L/g kW h achieved under the FO optimal conditions, 0.83 L/min feed flow rate, 0.31 L/min draw solution flow rate and 32.65 °C temperature. The FO energy consumption is only 14.1% the total energy consumption of the FO/RO hybrid system.
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