Landfill leachates from municipal landfills are usually heavily contaminated and thus require treatments before direct discharge into natural waters. Selecting the appropriate technology for leachate treatment is still a major challenge for operations in municipal landfills. Biodegradation is effective for treating young leachates, whereas old leachates require processes such as chemical oxidation, coagulation-flocculation, chemical precipitation, ozonation, activated carbon adsorption, and reverse osmosis. Recently, the combination of biological pretreatments followed by physico-chemical processes has been shown to be very efficient. Here we review the efficiency of biological treatment in combination with reverse osmosis to clean landfill leachates. We studied in particular processes including a membrane bioreactor, activated sludge, a rotating biological contactor, and up-flow anaerobic sludge blanket treatments, followed by reverse osmosis. We found a 99-99.5% removal of the chemical oxygen demand (COD), and a 99-99.8% removal of N-NH 4 + using reverse osmosis and activated sludge. Using reverse osmosis with a rotating biological contactor, we observed 99% removal of COD, biochemical oxygen demand and N-NH 4 + . The combination of reverse osmosis, activated sludge and rotating biological contactor removed 98-99.2% of Cl − and 99-99.7% of Pb. Total suspended solids are best removed, up to 99%, by either a combination of reverse osmosis with membrane bioreactor, or reverse osmosis with activated sludge.
This study aimed to determine the effect of the low-temperature conditioning of excess dairy sewage sludge using solidified carbon dioxide on the efficiency of methane fermentation. An increase in the solidified carbon dioxide to excess dairy sewage sludge volumetric ratio above 0.3 had no significant effect on chemical oxygen demand concentration in the dissolved phase. The highest chemical oxygen demand values, ranging from 490.6 ± 12.9 to 510.5 ± 28.5 mg·dm−3, were determined at solidified carbon dioxide to excess dairy sewage sludge ratio ranging from 0.3 to 0.5. The low-temperature conditioning caused ammonia nitrogen concentration to increase from 155.2 ± 10.2 to 185.9 ± 11.1 mg·dm−3 and orthophosphates concentration to increase from 198.5 ± 23.1 to 300.6 ± 35.9 mg·dm−3 in the dissolved phase. The highest unitary amount of biogas, reaching 630.2 ± 45.5 cm3·g o.d.m.−1, was produced in the variant with the solidified carbon dioxide to excess dairy sewage sludge volumetric ratio of 0.3. Methane content of the biogas produced was at 68.7 ± 1.5%. Increased solidified carbon dioxide dose did not lead to any significant changes in biogas and methane production. The efficiency of biogas production from unconditioned excess dairy sewage sludge was lower by 43.0 ± 3.2%. The analysis demonstrated that the low-temperature conditioning is an energetic viable technology aiding the methane fermentation process.
The development of a sustainable bioenergy market is currently largely fueled by energy crops, whose ever-increasing production competes with the global food and feed supply. Consequently, non-food crops need to be considered as alternatives for energy biomass production. Such alternatives include microalgal biomass, as well as energy crops grown on non-agricultural land. The aim of the present study was to evaluate how co-digestion of microalgal biomass with giant miscanthus silage affects feedstock properties, the biogas production process, biogas yields, methane fractions and the digestate profile. Combining giant miscanthus silage with microbial biomass was found to produce better C/N ratios than using either substrate alone. The highest biogas and methane production rates—628.00 ± 20.05 cm3/gVS and 3045.56 ± 274.06 cm3 CH4/d—were obtained with 40% microalgae in the feedstock. In all variants, the bulk of the microbial community consisted of bacteria (EUB338) and archaea (ARC915).
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