This work was carried out in collaboration between all authors. Author IEA, designed and supervised the execution of the project and handled the statistical analysis aspect of the research. He also supervised the writing of the manuscript and edited the final copy before it was sent out for consideration for publication. Author PAA joined the local residents in Fokoto collect the water samples and was in the laboratory for the water analysis. He wrote the laboratory reports and prepared the first draft of the manuscript which was edited by author IEA. All authors read and approved the final manuscript.
This study was aimed at analyzing the water quality of Ele River Nnewi, Anambra State for irrigation purposes with a view to predicting a one-year water quality index using Artificial Neural Network (ANN). Water pollution has posed a major problem and identifying the points of pollution in the River system is a very difficult task. To overcome this task, the need to determine the pollution level arose by modeling and predicting four water quality parameters at four (4) different locations using the Artificial Neural Network. These parameters include the pH, Total Dissolved Solids (TDS), Electrical Conductivity (EC), and Sodium (Na), respectively. The water quality results showed that the pH values which ranges from 6.01 to 6.87 were within the FAO standard in all the points for both rainy and dry seasons, whereas the TDS (mg/l), EC (dS/m) and Na (mg/l) parametric values range from 2001 to 2506, 3.01 to 5.76, and 40.42 to 73.45 respectively, were above the FAO standard from point 1 to point 3 and falls within the FAO standard at point 4 with values ranging from 1003 to 1994, 2.01 to 2.78 and 31.24 to 39.44, respectively. However, during the dry season, the TDS, EC, and Na values range from 2002 to 2742, 3.04 to 5.82 and 40.14 to 88.45 respectively, were all above the FAO standard. Generally, the artificial neural network modeled the actual water quality data set very well with good prediction. The training model performance evaluation shows that the R2 values ranges from 0.981 to 0.990, 0.981 to 0.988, 0.981 to 0.989 and 0981 to 0.989, for pH, TDS, EC, and Na. The testing model performance shows that the R2 value ranges from 0.952 to 0.967, 0.953 to 0.970, 0.951 to 0.967and 0.953 to 0.968, for pH, TDS, EC and Na while the forecast performance evaluation shows that the R2 values ranges from 0.945 to 0.968, 0.946 to 0.968, 0.944 to 0.967 and 0.949 to 0.965 for pH, TDS, EC and Na respectively. It was also observed that the Root Mean Squared Error (RMSE) ranges from 0.022 to 0.088, 0.012 to 0.087, 0.015 to 0.085 and 0.014 to 0.084 for pH, TDS, EC and Na, respectively. Information from this study will serve as a guide to researchers on the water quality index for irrigation purposes. Also, it will guide the government and agencies on policy, management and decision-making on water resources.
The Various physical mechanisms governing river flow dynamics act on a wide range of temporal and spatial scales. This spatio-temporal variability has been believed to be influenced by a large number of variables. In the light of this, an attempt was made in this paper to examine whether the daily flow sequence of the Benue River exhibits low-dimensional chaos; that is, if or not its dynamics could be explained by a small number of effective degrees of freedom. To this end, nonlinear analysis of the flow sequence was done by evaluating the correlation dimension based on phase space reconstruction and maximal Lyapunov estimation as well as nonlinear prediction. Results obtained in all instances considered indicate that there is no discernible evidence to suggest that the daily flow sequence of the Benue River exhibit nonlinear deterministic chaotic signatures. Thus, it may be conjectured that the daily flow time series span a wide dynamical range between deterministic chaos and periodic signal contaminated with additive noise; that is, by either measurement or dynamical noise. However, contradictory results abound on the existence of low-dimensional chaos in daily streamflows. Hence, it is paramount to note that if the existence of low-dimension deterministic component is reliably verified, it is necessary to investigate its origin, dependence on the space-time behavior of precipitation and therefore on climate and role of the inflow-runoff mechanism
The analysis of time series is essential for building mathematical models to generate synthetic hydrologic records, to forecast hydrologic events, to detect intrinsic stochastic characteristics of hydrologic variables as well to fill missing and extend records. To this end, this paper examined the stochastic characteristics of the monthly rainfall series of Ilorin, Nigeria vis-à-vis modelling of same using four modelling schemes. The Decomposition, Square root transformation-deseasonalisation, Composite, and Periodic Autoregressive (T-F) modelling schemes were adopted. Results of basic analysis of the stochastic characteristics revealed that the monthly series does not show any discernible presence of long-term trend, though there is a seeming inter-decadal annual variation. The series exhibits strong seasonality throughout its length, both in the moments and autocorrelation and significantly intermittent. Based on assessment of the respective models, the performance of the different modelling schemes can be expressed in this order: T-F > Composite > Square root transformation-Deseasonalised > Decomposition. Considering the results obtained, modelling of monthly rainfall series in the presence of serial correlation between months should be based on the establishment of conditional probability framework. On the other hand, in view of the inadequacy of these modelling schemes, because of the autoregressive model components in the coupling protocol, nonlinear deterministic methods such as Artificial Neural Network, Wavelet models could be viable complements to the linear stochastic framework.
Oil pollution causes deterioration of the physical, chemical, mechanical, and geotechnical characteristics of affected soil leading to loss of soil productivity for engineering purposes. Different stabilization methods serve as a remedy for such soil to regain its loss engineering properties. This study was concerned with the utilization of lime to stabilize crude oil contaminated soil and to investigate its efficacy for soil stabilization. The study also focused on determining the geotechnical properties of crude oil contamination and matching the result with standard specifications established for engineering works. Hydrated lime, expansive clayey soil, contaminated soil, and potable water were the materials used for the experimental investigation. The contaminated soil was treated with 6.5% lime and 0–20% crude oil contaminated materials obtained from oil exploration sites in North-Eastern Nigeria and per standard test method for laboratory evaluation of consistency limits, compaction properties, California bearing ratio (CBR), and microstructural and mineralogical assessments. The experimental results obtained were further tested statistically through one-way ANOVA and F-statistics to establish the source of variation for the geotechnical properties, while multiple linear regression and correlation statistics helped draw the connection between the consistency limits, compaction, and CBR properties of the soil-lime-COCM blend. Results indicated a coefficient of determination of 99.86. The contaminated soil materials were found to show optimal performance at a 5% ratio and 6.5% of lime for civil construction purposes.
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