It is shown that high operational reliability of structural materials, in particular at high temperatures, is achieved through the use of ultra-high strength cement composites. Studies of various types of Portland cements with mineral additives of the CEM II/A type have established that a stone based on Portland cement with superzeolite is the most resistant to high temperatures. It has been proven that due to the "self-autoclaving" effect, the strength of a stone based on CEM II/A-P 42.5 R is 1.2–1.3 times higher than a stone based on other types of CEM II/A. To obtain fast-hardening cement composites, a nanotechnological approach based on the use of sol-gel technology has been implemented. Using the methods of IR spectroscopy, electron microscopy, the fact of obtaining, by the chemical method of synthesis, an alkaline nanomodifier N-C-S-H-PCE, which is a nano–liquid based on nano-core seeds of sodium/calcium hydrosilicates, has been proved. It has been confirmed that the introduction of the alkaline nanomodifier N-C-S-H-PCE provides a significant intensification of the early structure formation processes in the paste based on Portland cement with superzeolite (after 12 hours, 24 hours and 28 days, the strength is 16.9; 30.5 and 104.1 MPa). It has been established that the complex combination of Portland cement with superzeolite, corundum aggregate, basalt fiber and alkaline nanomodifier provides rapid-hardening of ultra-high strength cement composites (T=400 °C) with improved operational properties. Thus, there is reason to assert the feasibility of developing rapid-hardening ultra-high strength cementitious composites. This solves the problems associated with the need to increase their early strength and performance. As a result, it is possible to carry out repair work to protect equipment from abrasive wear at elevated temperatures
The article shows the relation between sustainability and cement manufacture that can be obtained by the replacement of clinker with limestone additive. This decreases the use of energy resources and reduces CO2 emissions in cement production. The issue of partial Portland cement clinker substitution by finely ground limestone in the production of market-oriented types of cement type CEM II is solved on the cement plant PJSC "Ivano-Frankivsk Cement". The indexes of physical-mechanical tests of certified Portland limestone cement with high early strength CEM II/A-LL 42.5 R produced by PJSC "Ivano-Frankivsk Cement" are given. Finely dispersed limestone in Portland-composite cements with slag promotes a more complete synergic effect. It is established, that rapid-hardening blended Portland cements with limestone powder provide technological, technical, ecological, and economic effects in the production of prefabricated and monolithic reinforced concrete.
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