In this paper, we report a study on the effects of different ethylene copolymers in improving the impact strength of a fiber-reinforced composite based on a recycled poly(ethylene terephthalate) (rPET) from post-consumer bottles. Different ethylene copolymers have been selected in order to evaluate the effects of the polar co-monomer chemical structure and content. The composite mixtures were prepared via melt extrusion, and the samples were manufactured by injection molding. Impact strength was evaluated using Izod tests, and a morphological study (FESEM) was performed. As a result, a composite with substantially improved impact properties was designed. This study demonstrates that a post-consumer PET from the municipal waste collection of plastic bottles can be successfully used as a matrix of high-performance, injection-molded composites, suitable for use in the automotive sector, among others, with no compromise in terms of mechanical requirements or thermal stability.
Biophosphors with fluorescent proteins (FPs) are promising candidates to replace rare‐earth color down‐converting filters for white light‐emitting diodes (LEDs). There is, however, a lack of deep‐red FPs meeting high photostabilities, photoluminescence quantum yields (ϕ), and throughput expression yields. Herein, a new approach for the design of highly emissive and stable deep‐red biophosphors combining an artificial FP (Lactococcal multidrug resistance Regulator (LmrR) as protein host and an archetypal red‐emitting squaraine (S) as guest) with a polymer network is demonstrated toward high performing deep‐red biohybrid LEDs (Bio‐HLEDs). At first, the best protein pocket (aromaticity, polarity, charge, etc.) to stabilize S in water is determined using four LmrR variants (position 96 with tryptophan, histidine, phenylalanine, and alanine). Computational and time‐resolved spectroscopic findings suggest that the tryptophan is instrumental toward achieving artificial red‐emitting FPs with ϕ > 50% stable over weeks. These features are further enhanced in the polymer coating (ϕ > 65% stable over months) without affecting emission color. Finally, deep‐red Bio‐HLEDs are fabricated featuring external quantum efficiencies of 7% and stabilities of ≈800 h. This represents threefold enhancement compared to reference devices with S‐polymer color filters. Overall, this work highlights a new design for highly emissive deep‐red biophosphors, achieving record performance in deep‐red protein‐LEDs.
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