This study investigated the effects of processing parameters, namely particle mixing ratios, press temperatures, and time for the manufacturing of jute stick binderless particleboard (JBPB). Different ratios of fine and coarse particles, press temperature (160 to 240 °C) and press time (4 to 10 min) were used for JBPB fabrication with a target density of 0.9 g/cm3. The dimensional stability and mechanical properties of JBPB were determined according to Japanese Industrial Standard JIS A 5908 (2003). The result shows that the most favorable pressing conditions in the manufacturing process were press temperature of 220 °C for 6 min with a mixing ratio of 50:50 (fine: coarse). The modulus of rupture (MOR), modulus of elasticity (MOE), and internal bonding (IB) of JBPB was 16.35 N/mm2, 3872.99 N/mm2, and 1.07 N/mm2, respectively, which met the minimum requirement for type-18 of particleboard JIS A 5908 (2003) except for the value of MOR. The bonding mechanism was analyzed by the chemical changes in the raw materials after the fabrication of JBPBs. The pentosans present in the raw material decreased with the increased press temperatures. In this study, the hemicellulose was decomposed which may accelerate the self-bonding of the JBPB at high temperatures. The thermal gravimetric analysis (TGA) revealed that the JBPB showed good thermal stability with the increase of press temperatures. Fourier transform infrared (FTIR) spectra indicated that the removal of hydroxyl groups which increased the dimensional stability of JBPBs. Hence, it could be concluded that by controlling particle mixing ratio (50:50) at high press temperature with proper press time, high-performance jute stick binderless particleboard could be successfully developed which has a variety of applications.
The application of citric acid and glycerol as natural binder was investigated for the manufacturing of jute stick particleboard in this study. The effects of citric acid content (0–30 wt%), citric acid and glycerol mixture (ratio of CA–G), and pressing temperatures on the properties of jute stick particleboard were investigated. Citric acid-bonded jute stick particleboard had good mechanical properties and dimensional stability when citric acid concentration was 20 wt% at pressing temperature of 200 °C. By addition of glycerol concentration (40/60), the properties were further increased. The modulus of rupture (MOR) and thickness swelling (TS) values of CA–G (40/60) bonded jute stick particleboard were 19.67 N/mm2 and 9%, respectively, which satisfy the minimum requirement for type-18 of particleboard JIS A 5908 (2003). FTIR analysis confirmed the formation of ester linkage by polymerization reaction between carboxyl groups and alcohol groups. Citric acid and glycerol polymer reacted with jute stick particles and produced cross-linked networks with enhanced properties, hence improved the adhesiveness during particleboard production. It could be concluded that citric acid and glycerol mixture can be a potential natural binder for the production of jute stick particleboard.
Studies about manufacturing of synthetic adhesive-free binderless particleboards from nonwood lignocellulosic materials have come under limelight as a consequence of wood supplies reduction along with the demand for formaldehyde-free panels. The overview of binderless particleboard's development from different agricultural waste using an assorted range of manufacturing processes and their self-bonding mechanisms are presented in this chapter. Also, the features of different manufacturing parameters of binderless particleboards, such as pressing temperature and pressure, pressing time, particle size, mixing ratio and additional substances, are discussed. The physical, mechanical, and biological properties of every binderless particleboard are typically evaluated. This chapter provides a big picture of previous researches of binderless particleboards from different lignocellulosic agricultural waste with better understanding of their self-bonding mechanisms, contributing factors, and the manufacturing processes in favor of future value-added environmental friendly binderless particleboards.
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