Developing efficient seawater-electrolysis system for mass production of hydrogen is highly desirable due to the abundance of seawater. However, continuous electrolysis with seawater feeding boosts the concentration of sodium chloride in the electrolyzer, leading to severe electrode corrosion and chlorine evolution. Herein, the common-ion effect was utilized into the electrolyzer to depress the solubility of NaCl. Specifically, utilization of 6 M NaOH halved the solubility of NaCl in the electrolyte, affording efficient, durable, and sustained seawater electrolysis in NaCl-saturated electrolytes with triple production of H2, O2, and crystalline NaCl. Ternary NiCoFe phosphide was employed as a bifunctional anode and cathode in simulative and Ca/Mg-free seawater-electrolysis systems, which could stably work under 500 mA/cm2 for over 100 h. We attribute the high stability to the increased Na+ concentration, which reduces the concentration of dissolved Cl- in the electrolyte according to the common-ion effect, resulting in crystallization of NaCl, eliminated anode corrosion, and chlorine oxidation during continuous supplementation of Ca/Mg-free seawater to the electrolysis system.
Tidal range energy is one of the most predictable and reliable sources of renewable energy. This study’s main aim is to determine potential sites for tidal range power in East Malaysia, by analyzing tidal range distributions and resources and the feasibility of constructing barrages. Investigation was conducted in 34 sites, estimating their potential energy outputs and studying their areas for constructing barrages. Only 18 sites were marked as appropriate for constructing a tidal range energy extraction barrage. The highest potential power was found in Tanjung Manis, and its maximum capacity was calculated as 50.7kW. The second highest potential of tidal power extraction was found in Kuching Barrage at Pending, where an energy harvester could produce electric power up to 33.1kW.
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