Steel pipelines externally exposed to seawater pit more severely in heat-affected weld zones but longer-term quantitative data are scarce. Maximum pit depths and variability are reported for the longitudinal weld in API X56 Spec 5 L grade steel pipeline samples exposed continuously to natural Pacific Ocean seawater for 3.5 years. For the first year maximum pit depths and pit depth variability for the different weld zones were very similar. Both became much greater subsequently, with the greatest increases for the heat affected zone. This is compared with steel composition and grain size and potential reasons for the observations discussed.
Localised or pitting corrosion can be detrimental for steel pipes and containment structures, since wall perforation may cause system failure. Herein maximum pit depth quantification and its development with time are considered for samples taken from longitudinal welds on 33-year-old tubulars exposed in Newcastle Harbour. Relationships between pit depth and material metallurgy and corrosion properties were investigated by means of standard macro-etching, rest potential and zero resistance ammetry techniques. It is considered that the observed results are the result of the lack of homogeneity at the corrosion interface caused by differences in grain size, grain structure and the potential for pitting to occur preferentially along boundaries. The results are compared to measurements for longitudinal welds obtained previously on samples of API X56 Spec 5L pipe exposed in similar waters for up to 3?5 years, showing a reasonable degree of consistency between the two sets of data. The reasons for this are discussed.
After more than 75 years continuous exposure to the Pacific Ocean waters on the Queensland coast the 879 reinforced concrete driven piles that supported the superstructure of the Hornibrook Highway bridge appeared to be in remarkably good condition when the bridge was demolished during 2011-2. Detailed investigations revealed excellent, very hard concrete with pH values still around 12 and very little evidence of serious corrosion of the steel reinforcement. The concrete chloride content at the reinforcement was considerably more than the usually accepted limits. However, a few isolated occurrences of very severe localized reinforcement corrosion were found during demolition even though there was little visual external evidence. Possible reasons for the various observations are discussed, together with the practical implications.
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