Highlights SOC stocks were modelled using legacy data, environmental factors and geostatistics. The importance of SOC stock drivers differed in the top and subsoil. Effects of drivers on agricultural SOC stocks vary spatially at the regional scale. SOC stocks in Catalan agricultural soils contain 4.88 ± 0.89 kg/m 2 .  A baseline framework was established to design climate change mitigation strategies.

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Water resources in high mountain karst aquifers are usually characterized by high rainfall, recharge and discharge that lead to the sustainability of the downstream ecosystems. Nevertheless, these hydrological systems are vulnerable to the global change impact. The mean transit time (MTT) is a key parameter to describe the behavior of these hydrologic systems and also to assess their vulnerability. This work is focused on estimating MTT by using environmental tracers in the framework of high-mountain karst systems with a very thick unsaturated zone (USZ). To this end, it is adapted to alpine zones a methodology that combines a semi-distributed rainfall-runoff model to estimate recharge time series, and a lumped-parameter model to obtain ΜΤΤ. The methodology has been applied to the Port del Comte Massif (PCM) hydrological system (Southeastern Pyrenees, NE Spain), a karst aquifer system with an overlying1000 m thick USZ. Six catchment areas corresponding to most important springs of the system are considered. The obtained results show that hydrologically the behavior of the system can be described by an exponential flow model (EM), with MTT ranging between 1.9 and 2.9 years. constant recharge rate along time, which is the easiest and most applied -parameter models.Response to Reviewers: COMMENTS FROM REVIEWERS: Reviewer #1 General commentsThee paper by Herms et al. with title: "Contribution of isotopic research techniques to characterize high mountain-Mediterranean karst aquifers: The Port del Comte (Eastern Pyrenees) aquifer." provides an interesting study regarding the contribution of isotopic research in karst aquifers. The concept is interest and the manuscript well written.Thank you very much for your kind comments However, I have a number of recommendations, which should be done before publication.

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The Water Framework Directive (WFD) requires EU member states to assess the chemical status of groundwater bodies, a status defined according to threshold values for harmful elements and based on/the natural background level (NBL). The NBL is defined as the expected value of the concentration of elements naturally present in the environment. The aim of this study is to propose a methodology that will be broadly applicable to a wide range of conditions at the regional and national scale. Using a statistical approach, the methodology seeks to determine NBLs for SO4, As, Cd, Cr, Cu, Ni, Zn, and F based on the lithology of aquifers from which groundwater monitoring data were collected. The methodology was applied in six EU countries to demonstrate validity for a wide range of European regions. An average concentration was calculated for each parameter and chosen water point and linked to a lithology. Based on the dataset created, significant differences between lithologies and pressure categories (urban, agricultural, industrial, and mining) were tested using a nonparametric test. For each parameter, 90th percentiles were calculated to provide an estimation of the maximum natural concentrations possible for each lithology.

This document presents a comprehensive review of research works, regulatory frameworks, technical solutions, and commercial trends related to the integration of shallow geothermal energy (SGE) technologies in modern 5th-generation district heating and cooling (5GDHC) networks. This literature and market analysis is contextualized by the present geopolitical, environmental, and societal scenario in Europe. In this sense, decarbonization of the heating and cooling sector is a crucial piece in the energy transition puzzle to keep global warming below the critical threshold of 1.5 °C by the next century. Moreover, Ukraine war has added urgency to end up with fossil fuel dependency. The most relevant outcome of this literature review is the synergistic relationship between SGE, 5GDHC networks, and urban environments. SGE is most efficiently deployed in urban environments when it is part of a district heating and cooling network, and the modern concept of 5GDHC is the most suitable scenario for it. Since the potential contribution of SGE to the decarbonization of the heating and cooling supply is mostly untapped across Europe, this synergistic effect represents a possible boost. Hybridization with solar photovoltaics and/or storage makes it even more attractive. Outstanding cases are reviewed, challenges for the future are presented, and tools to overcome social reluctance and/or lack of awareness are described, along with a discussion of the stimuli for the deployment of SGE and 5GDHC networks. A particular focus on Mediterranean countries is presented, where SGE systems and DHC networks of any kind show a particularly low deployment compared to the rest of Europe. To this end, the second part of this work evaluates, justifies, and analyzes the possibilities and potentialities of their application in this zone.

The assessment of the deep geothermal potential is an essential task during the early phases of any geothermal project. The well-known “Heat-In-Place” volumetric method is the most widely used technique to estimate the available stored heat and the recoverable heat fraction of deep geothermal reservoirs at the regional scale. Different commercial and open-source software packages have been used to date to estimate these parameters. However, these tools are either not freely available, can only consider the entire reservoir volume or a specific part as a single-voxel model, or are restricted to certain geographical areas. The 3DHIP-Calculator tool presented in this contribution is an open-source software designed for the assessment of the deep geothermal potential at the regional scale using the volumetric method based on a stochastic approach. The tool estimates the Heat-In-Place and recoverable thermal energy using 3D geological and 3D thermal voxel models as input data. The 3DHIP-Calculator includes an easy-to-use graphical user interface (GUI) for visualizing and exporting the results to files for further postprocessing, including GIS-based map generation. The use and functionalities of the 3DHIP-Calculator are demonstrated through a case study of the Reus-Valls sedimentary basin (NE, Spain).