The field of nanofluids has received interesting attention since the concept of dispersing nanoscaled particles into a fluid was first introduced in the later part of the twentieth century. This is evident from the increased number of studies related to nanofluids published annually. The increasing attention on nanofluids is primarily due to their enhanced thermophysical properties and their ability to be incorporated into a wide range of thermal applications ranging from enhancing the effectiveness of heat exchangers used in industries to solar energy harvesting for renewable energy production. Owing to the increasing number of studies relating to nanofluids, there is a need for a holistic review of the progress and steps taken in 2019 concerning their application in heat transfer devices. This review takes a retrospective look at the year 2019 by reviewing the progress made in the area of nanofluids preparation and the applications of nanofluids in various heat transfer devices such as solar collectors, heat exchangers, refrigeration systems, radiators, thermal storage systems and electronic cooling. This review aims to update readers on recent progress while also highlighting the challenges and future of nanofluids as the next-generation heat transfer fluids. Finally, a conclusion on the merits and demerits of nanofluids is presented along with recommendations for future studies that would mobilise the rapid commercialisation of nanofluids.

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Solar thermal collectors are systems that allow for the use of solar energy in thermal applications. These collectors utilize a heat transfer fluid to transport absorbed solar radiation to applications where they are needed. Scientists in a bid to improve the conversion efficiency of solar collectors have suggested different collector designs and improved collector materials. Over the last 25 years, the study of nanofluids and their applications have revolutionized material science, and nanotechnology has found applications in improving solar collector materials. This article reviews the impact of different nanomaterials on the efficiency of solar collectors. The study also outlines the limitations of applying nanofluids and discusses the long-term challenges of their application to solar collectors. Nanofluids have the potential to improve the overall efficiency of most solar collectors, however, the full potential of nanofluids in heat transfer applications cannot be completely achieved until some of the questions regarding hysteresis, stability, and the overall predictability of nanofluids are answered.

Hybrid nanofluids are better heat transfer fluids than conventional nanofluids because of the combined properties of two or more nanoparticles. In this study, the thermal conductivity of Al 2 O 3-ZnO nanoparticles suspended in a base fluid of distilled water is investigated. The experiments were conducted for three mixture ratios (1:2, 1:1 and 2:1) of Al 2 O 3-ZnO nanofluid at five different volume concentrations of 0.33%, 0.67%, 1.0%, 1.33% and 1.67%. X-ray diffractometric analysis, X-ray fluorescence spectrometry and scanning electron microscopy were used to characterise the nanoparticles. The highest thermal conductivity enhancement achieved for Al 2 O 3-ZnO hybrid nanofluids with 1:2, 1:1 and 2:1 (Al 2 O 3 :ZnO) mixture ratios was 36%, 35% and 40%, respectively, at volume concentration 1.67%. The study observed the highest thermal conductivity for Al 2 O 3-ZnO nanofluid was achieved at a mixture ratio of 2:1. A "deeping" effect was observed at a mixture ratio of 1:1 representing the lowest value of thermal conductivity within the considered range. The study proposed and compared three models for obtaining the thermal conductivity of Al 2 O 3-ZnO nanofluids based on temperature, volume concentration and nanoparticle mixture ratio. A polynomial correlation model, the adaptive neuro-fuzzy inference system model and an artificial neural network model optimised with three different learning algorithms. The adaptive neuro-fuzzy inference system model was most accurate in forecasting the thermal conductivity of the Al 2 O 3-ZnO hybrid nanofluid with an R 2 value of 0.9946.

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