The accumulation of soiling on photovoltaic (PV) modules affects PV systems worldwide. Soiling consists of mineral dust, soot particles, aerosols, pollen, fungi and/or other contaminants that deposit on the surface of PV modules. Soiling absorbs, scatters, and reflects a fraction of the incoming sunlight, reducing the intensity that reaches the active part of the solar cell. Here, we report on the comparison of naturally accumulated soiling on coupons of PV glass soiled at seven locations worldwide. The spectral hemispherical transmittance was measured. It was found that natural soiling disproportionately impacts the blue and ultraviolet (UV) portions of the spectrum compared to the visible and infrared (iR). Also, the general shape of the transmittance spectra was similar at all the studied sites and could adequately be described by a modified form of the Ångström turbidity equation. In addition, the distribution of particles sizes was found to follow the IEST-STD-CC 1246E cleanliness standard. The fractional coverage of the glass surface by particles could be determined directly or indirectly and, as expected, has a linear correlation with the transmittance. It thus becomes feasible to estimate the optical consequences of the soiling of pV modules from the particle size distribution and the cleanliness value. Soiling has a negative impact on the economic revenues of PV installations, not only because it reduces the amount of energy converted by the PV modules, but also because it introduces additional operating and maintenance costs and, at the same time, increases the uncertainty on the estimation of PV performance, leading to both higher financial risks and interest rates charged to plant developers. Power reductions greater than 50% have been reported in the literature because of soiling 1,2 ; it has been estimated that an average loss of 4% on the global annual energy yield of PV could cause losses in revenue on the order of 2 × 10 9 US$ annually 3. A careful monitoring of soiling is required to mitigate its effect 4. Soiling losses are generally quantified by using soiling stations. These systems are made of at least two PV devices, one of which is regularly cleaned while the other is left to soil naturally. By comparing the ratio of the electrical outputs of the two devices, it is possible to estimate the impact of soiling on the PV performance 5,6. The International Electrotechnical Commission's (IEC) metric to monitor and quantify the impact of soiling on PV modules is the soiling ratio, r s , which expresses the ratio of the electrical output of a soiled PV device to the output of the same device under clean conditions 7. Like the transmittance, a higher soiling ratio translates to less soiling deposited on the modules. A value of 1 indicates clean conditions, with no soiling. For a more detailed definition of r s , please refer to the Methodology section. The fractional loss of solar-generated power due to soiling is 1 − r s .
The present work reports on the initial results of an international collaboration aiming to investigate the spectral effects of soiling losses. Identical glass coupons have been exposed outdoors for eight weeks in different locations worldwide, and weekly direct and hemispherical transmittance (T%) measurements are compared. Maximum losses as high as 7% and 50% in hemispherical and direct transmittance, respectively, have been found during the 8-week outdoor exposure. At the end of the data collection, a preliminary analysis of the spectral impact of soiling has been performed. The results show that the blue end of the spectrum is more affected and that lower hemispherical T% correlate to larger area covered by particles.
Commercial nano-WO 3 (10−100 nm average particle size) is dispersed in nhexanol and applied to tin-doped indium oxide (ITO) substrates in a simple "roll-on" process. As-deposited and annealed (500 °C) films are compared and shown to be photoactive for the formation of hypochlorite in neutral aqueous NaCl (e.g., seawater). Annealing at 500 °C in air improves photocurrents most likely due to improved interparticle charge transport (e.g., removal of hydration or n-hexanol surface layers). In phototransients (interpreted here in the limiting case of a weakly associated nanoparticle aggregate as opposed to the limiting case of a single-crystal semiconductor), evidence for the presence of both holes (as O(-I), fast moving) and electrons (as W(V), slow moving) is obtained in particular in as-deposited films. Bipotentiostat experiments reveal the presence of chlorine as a reaction intermediate close to the photoanode when immersed in 3 M NaCl. A "molecular conduit" effect with adsorbed Co(II/III) sepulchrate is observed to significantly enhance the photocurrents at as-deposited electrodes (but not at annealed electrodes).
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