Municipal solid waste (MSW) management remains a challenge in developing countries due to increasing waste generation, high costs associated with waste management and the structure of the containment systems implemented. This study analyses the classification of landfilling systems by using documented cases reported mainly in publications in waste management in relation to nonengineered landfilling systems/approved dumpsites in Sub Saharan African (SSA) countries from 2000 to 2018. The work identifies an existing system for the classification of landfill sites and utilises this system to determine the situation of landfill sites in SSA countries. Each article was categorised according to the main landfilling management practice reported: Uncontrolled dumping, semi controlled facility, medium controlled facility, medium/high-engineered facility or high state-of theart facility. Findings suggested that 80% of the documented cases of landfill sites assessed in SSA countries were classified as level 0 or 1. The structure of the containment and controlled regime were identified by the focus group discussion participants as important predictors of possible strengths, weaknesses, opportunities and threats for the landfill sites considered. The study represents the first identifiable and comprehensive academic evaluation of landfill site classification based on site operations reported in the available peer reviewed literature. The information provides insight on the status of landfill sites in SSA countries with respect to the landfilling management practice and a baseline for alternative corrective measures.
Proper management and safe disposal of medical waste (MW) is vital in the reduction of infection or illness through contact with discarded material and in the prevention of environmental contamination in hospital facilities. The management practices for MW in selected healthcare facilities in Lagos, Nigeria were assessed. The cross-sectional study involved the use of questionnaires, in-depth interviews, focused group discussions and participant observation strategies. It also involved the collection, segregation, identification and weighing of waste types from wards and units in the representative facilities in Lagos, Nigeria, for qualitative and quantitative analysis of the MW streams. The findings indicated that the selected Nigerian healthcare facilities were lacking in the adoption of sound MW management (MWM) practices. The average MW ranged from 0.01 kg/bed/day to 3.98 kg/bed/day. Moreover, about 30% of the domestic waste from the healthcare facilities consisted of MW due to inappropriate co-disposal practices. Multiple linear regression was applied to predict the volume of waste generated giving a correlation coefficient (R(2)) value of 0.99 confirming a good fit of the data. This study revealed that the current MWM practices and strategies in Lagos are weak, and suggests an urgent need for review to achieve vital reversals in the current trends.
Recently, due to its low cost there has been increased attention on Animal Waste Fats (AWFs) as a feedstock for biodiesel production. Advanced microwave technology has also been reported by many researchers to enhance the transesterification in biodiesel production. However, esterification of free fatty acids in the feedstock reported here has not attracted so much attention. AWFs come with its challenges namely, high free fatty acid (FFA) content and high water content. This study utilizes AWFs (tallow) containing very large amount of FFA; (25wt.%, 18 wt.%, and 9.4 wt.% FFA/AWFs) as feedstock for fatty acid methyl ester (FAME) production.A simple thermal pre-treatment technique followed microwave assisted esterification with methanol (MeOH) was conducted in a batch process to reduce the FFA content to as low as 1wt.% FFA, which is then suitable for the alkaline transesterification process. The pre-treatment of AWFs at 88°C to first reduce water and decrease viscosity, followed by an operating microwave power of 70W producing a power density 1.147mW/m 3 , achieved a 15% increase in reduction of FFA over 30W microwave power and conventional thermal method. Under optimum conditions, using 2.0 wt.wt% sulphuric acid catalyst/AWFs and 1:6 molar ratio AWF/MeOH, the FFA conversion of 93wt. % was achieved. The results indicated that the pre-treatment and microwave application provided a faster route to high FFA reduction of AWFs during esterification process. The proposed technology is promising for the potential scale up industrial application.
Mecoprop-p herbicide is often found in wells and water abstractions in many areas around Europe, the UK inclusive. There is a growing environmental and public health concern about mecoprop-p herbicide pollution in ground and surface water in England. Reviews suggest that extensive work has been carried out on the contribution of mecoprop-p herbicides from agricultural use whilst more work needs to be carried out on the contribution of mecoprop-p herbicide from non-agricultural use. The study covers two landfill sites in Weaver/Gowy Catchment. Mecoprop-p herbicide concentrations in the leachate quality range between 0.06 and 290 microg l1 in cells. High concentration ofmecoprop-p herbicide in the leachate quality suggests that there is a possible source term in the waste stream. This paper addresses the gap by exploring possible source terms of mecoprop-p herbicide contamination on landfill sites and evaluates the impact of public purchase, use and disposal alongside climate change on seasonal variations in mecoprop-p concentrations. Mecoprop-p herbicide was found to exceed the EU drinking water quality standards at the unsaturated zone/aquifer with observed average concentrations ranging between 0.005 and 7.96 microg l1. A route map for mecoprop-p herbicide source term contamination is essential for mitigation and pollution management with emphasis on both consumer and producer responsibility towards use of mecoprop-p product. In addition, improvement in data collection on mecoprop-p concentrations and detailed seasonal herbicide sales for non-agricultural purposes are needed to inform the analysis and decision process.
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