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thickness, we estimate that the volume of oil, including oil thicker than can be probed in the AVIRIS imagery, is possibly as high as 150,000 barrels in the AVIRIS scenes. When this value is projected to the entire spill, it gives a volume of about 500,000 barrels for thick oil remaining on the sea surface as of May 17. AVIRIS data cannot be used to confirm this higher volume, and additional field work including more in-situ measurements of oil thickness would be required to confirm this higher oil volume. Both the directly detected minimum range of oil volume, and the higher possible volume projection for oil thicker than can be probed with NIR spectroscopy imply a significantly higher total volume of oil relative to that implied by the early NOAA (National Oceanic and Atmospheric Administration) estimate of 5,000 barrels per day reported on their Web site.

Emissions estimates of anthropogenic methane (CH4) sources are highly uncertain and many sources related to energy production are localized yet difficult to quantify.Airborne imaging spectrometers like the next generation Airborne Visible/Infrared Imaging Spectrometer (AVIRIS-NG) are well suited for locating CH4 point sources due to their ability to map concentrations over large regions with the high spatial resolution necessary to resolve localized emissions. AVIRIS-NG was deployed during a field campaign to measure controlled CH4 releases at the Rocky Mountain Oilfield Testing Center (RMOTC) in Wyoming, U.S. for multiple flux rates and flight altitudes. Two algorithms were applied to AVIRIS-NG scenes, a matched filter detection algorithm and a hybrid retrieval approach using the Iterative Maximum a Posteriori Differential Optical Absorption Spectroscopy (IMAP-DOAS) algorithm and Singular Value Decomposition.Plumes for releases as low as 14.16 m 3 /h (0.09 kt/year) were consistently observed by AVIRIS-NG at multiple flight altitudes and images of plumes were in agreement with wind directions measured at ground stations. In some cases plumes as low as 3.40 m 3 /h (0.02 kt/year) were detected, indicating that AVIRIS-NG has the capability of detecting a wide range of fugitive CH4 source categories for natural gas fields. This controlled release experiment is the first of its kind using AVIRIS-NG and demonstrates the utility of imaging spectrometers for direct attribution of emissions to individual point source locations. This is particularly useful given the large uncertainties associated with anthropogenic CH4 emissions, including those from industry, gas transmission lines, and the oil and gas sectors.

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