Conjugated polymers enable the production of flexible semiconductor devices that can be processed from solution at low temperatures. Over the past 25 years, device performance has improved greatly as a wide variety of molecular structures have been studied. However, one major limitation has not been overcome; transport properties in polymer films are still limited by pervasive conformational and energetic disorder. This not only limits the rational design of materials with higher performance, but also prevents the study of physical phenomena associated with an extended π-electron delocalization along the polymer backbone. Here we report a comparative transport study of several high-mobility conjugated polymers by field-effect-modulated Seebeck, transistor and sub-bandgap optical absorption measurements. We show that in several of these polymers, most notably in a recently reported, indacenodithiophene-based donor-acceptor copolymer with a near-amorphous microstructure, the charge transport properties approach intrinsic disorder-free limits at which all molecular sites are thermally accessible. Molecular dynamics simulations identify the origin of this long sought-after regime as a planar, torsion-free backbone conformation that is surprisingly resilient to side-chain disorder. Our results provide molecular-design guidelines for 'disorder-free' conjugated polymers.

No abstract

The report presents the results from experimental investigation of micropinch formation in the plasma of a vacuum discharge induced by a 6 ns laser pulse of energy J = 0.5–200 mJ (at a storage voltage from 4 to 15 kV and the discharge current range of 6–26 kA, respectively). The discharge gap images were obtained using a pinhole camera in the EUV and soft X-ray ranges of 15–73 eV and 80–284 eV energy. It is shown that micropinch formation in the plasma cathode jet occurs, mainly, in the matter evaporated by the laser pulse at the discharge ignition near the moment when the current derivative reaches the maximum. It is found that the cathode jet may consist of several pinched areas, and each of them has its own structure, and the improvement of the discharge and laser radiation parameters allows us to reach a stable single pinching of plasma. The parameters of the micropinch (the plasma compression ratio, size, and position of the emitting area in the interelectrode gap) as well as the current flow through the interelectrode gap, at the given storage voltage, are completely governed by the laser radiation characteristics.

The formation of a current-plasma shell is studied during the expansion of a laser-ignited low-power vacuum-discharge cathode plasma jet into the interelectrode gap. The shell geometry is found to be determined by the mode of laser-plasma expansion at the discharge ignition stage. It is shown that the increase in the laser-beam focal spot area on the cathode surface leads to the increase in the matter density and the decrease in the density gradient in the discharge gap and to transition from the spherical laser-plasma expansion mode to the jet mode. The latter considerably stabilizes the current transfer in the discharge plasma, even during the development of the hydrodynamic sausage instability in it.

No abstract