Reaction of the phosphinous chlorides (Ia) and (Ib) or the phosphorochloridites (Ic) and (Id) with the phosphonium salt (II), the phosphorane (IV), or the carbodiphosphorane (V) and subsequent oxidation give the phosphorylated phosphoranes (III).
Reaction of the phosphinous chloride (I) with the phosphorane (II) and subsequent oxidation give the diphenylphosphinylacetyl‐substituted phosphorane (IIIa), oxidation of the phosphino compound (IV) produces the corresponding benzoyl derivative (IIIb).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.