Unzipping multiwall carbon nanotubes (MWCNTs) attracted great interest as a method for producing graphene nanoribbons (GNRs). However, depending on the production method, the GNRs have been proposed to form by different mechanisms. Here, we demonstrate that the oxidative unzipping of MWCNTs is intercalation-driven, not oxidative chemical-bond cleavage as was formerly proposed. The unzipping mechanism involves three consecutive steps: intercalation-unzipping, oxidation, and exfoliation. The reaction can be terminated at any of these three steps. We demonstrate that even in highly oxidative media one can obtain nonoxidized GNR products. The understanding of the actual unzipping mechanism lets us produce GNRs with hybrid properties varying from nonoxidized through heavily oxidized materials. We answer several questions such as the reason for the innermost walls of the nanotubes remaining zipped. The intercalation-driven reaction mechanism provides a rationale for the difficulty in unzipping single-wall and few-wall CNTs and aids in a reevaluation of the data from the oxidative unzipping process.

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Thin epitaxial films of the palladium-rich Pd 1−x Fe x alloy were synthesized and extensively studied as a tunable ferromagnetic material for superconducting spintronics. The (001)-oriented MgO single-crystal substrate and the composition range of x = 0.01-0.07 were chosen to support the epitaxial growth and provide the films with magnetic properties spanning from very soft ferromagnet for memory applications to intermediately soft and moderately hard for the programmable logic and circuit biasing, respectively. Dependences of the saturation magnetization, Curie temperature and three magnetic anisotropy constants on the iron content x were obtained for the first time from the analyses of the magnetometry and ferromagnetic resonance data. The experimental results were discussed based on existing theories of dilute ferromagnetic alloys. Simulation of the hysteresis loops within the Stoner-Wohlfarth model indicates the predominant coherent magnetic moment rotation at cryogenic temperatures. The obtained results were compiled in a database of magnetic properties of a palladium-iron alloy in a single-crystal thin-film form considered as a material for superconducting spintronics.