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The permanent structure induced by an Ar þ linearly polarised laser beam on an asymmetric dye-doped nematic liquid crystal cell was investigated in a pump-probe experiment. The polarisation direction of the probe beam was parallel to the easy axis and two configurations of pump beam were used: polarisation directions perpendicular and parallel to the easy axis. The transmitted intensity of the probe beam was recorded during irradiation and it was observed that it depended both on the power and polarisation direction of the pump beam. We explained the evolution of the transmitted intensity and evaluated the start time of formation of the ripple structure. The induced permanent structure in the irradiated zones and the laser-induced surface morphology was studied using a polarising optical microscope and an atomic force microscope, respectively. The surface morphology in the irradiated zones was also dependent on both the power and polarisation of the Ar þ laser beam. The orientation of the microgrooves in the ripple structure was parallel to the polarisation direction of the pump laser beam in both configurations. For a given pump power, the depth of the ripple structure was greater in the case of an Ar þ beam polarised parallel to the easy axis. The induced azimuthal anchoring energy provided by the ripple structure was evaluated.

We have investigated the role of the easy axis in the photoalignment effect induced by an Ar+ linearly polarized laser beam on a dye-doped nematic liquid crystal cell in a pump–probe experiment. The induced permanent structure in the irradiated zones was studied using a polarizing optical microscope, and the laser-induced surface morphology was studied by atomic force microscopy. The depth of the ripple structure depends on both the pump power and the irradiated surfaces. The azimuthal anchoring energy provided by the ripple structure was evaluated and it was concluded that it varies with the cell's symmetry.

Two yellow bis-azo dyes containing anthracene and two azodiphenylether groups (BPA and BTA) were prepared, and an extensive investigation of their physical, thermal and biological properties was carried out. The chemical structure was confirmed by the FTIR spectra, while from the UV–Vis spectra, the quantum efficiency of the laser fluorescence at the 476.5 nm was determined to be 0.33 (BPA) and 0.50 (BTA). The possible transitions between the energy levels of the electrons of the chemical elements were established, identifying the energies and the electronic configurations of the levels of transition. Both crystals are anisotropic, the optical phenomenon of double refraction of polarized light (birefringence) taking place. Images of maximum illumination and extinction were recorded when the crystals of the bis-azo compounds rotated by 90° each, which confirms their birefringence. A morphologic study of the thin films deposited onto glass surfaces was performed, proving the good adhesion of both dyes. By thermal analysis and calorimetry, the melting temperatures were determined (~224–225 °C for both of them), as well as their decomposition pathways and thermal effects (enthalpy variations during undergoing processes); thus, good thermal stability was exhibited. The interaction of the two compounds with collagen in the suede was studied, as well as their antioxidant activity, advocating for good chemical stability and potential to be safely used as coloring agents in the food industry.