This study presents the influence of rainfall and human perturbation on physical and chemical weathering rates, and carbon and nutrient yields in the basin of the Kaoping, a small mountainous river (SMR) in southwestern Taiwan. The study was derived principally from the spatial and temporal variability of aquatic geochemistry in the river during wet (1999–2000) and drought (2002) periods. The total, physical, and chemical weathering rates in the river basin ranged respectively from 4739, 3601, and 1138 g m−2 year−1 in the wet period to 1072, 656, and 416 g m−2 year−1 in the drought period, resulting mainly from a large difference in rainfall and river discharge between the two periods. The wet and drought periods were likely associated with La Niña and El Niño events, respectively. The weathering rates of the wet period were much higher than those reported from the world’s river basins, showing the unique characteristics of the SMR. The total carbon yield was derived mainly from dissolved inorganic carbon and was much higher in the wet period (140 g C m−2 year−1) than in the drought period (53.7 g C m−2 year−1). Taking silicate weathering (54.7 ± 10.2%) slightly over carbonate weathering (48.6 ± 9.5%) in determining dissolved ion loads, the Kaoping catchment may currently consume 0.155–0.298 MtC/year atmospheric CO2 without considering the CO2 released from chemical weathering. The nutrient yields were controlled mainly by human inputs but also enhanced by increased rainfall. Both regional and local climatic conditions and human impacts likely determined the weathering rates and total yields of carbon and nutrients. The SMRs may collectively contribute significantly to global fluxes of terrestrial sediments, geochemical matters, carbon, and nutrients to oceans.

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