The need for remediation of poly‐ and perfluoroalkyl substances (PFASs) is growing as a result of more regulatory attention to this new class of contaminants with diminishing water quality standards being promulgated, commonly in the parts per trillion range. PFASs comprise >3,000 individual compounds, but the focus of analyses and regulations has generally been PFASs termed perfluoroalkyl acids (PFAAs), which are all extremely persistent, can be highly mobile, and are increasingly being reported to bioaccumulate, with understanding of their toxicology evolving. However, there are thousands of polyfluorinated “PFAA precursors”, which can transform in the environment and in higher organisms to create PFAAs as persistent daughter products.
Some PFASs can travel miles from their point of release, as they are mobile and persistent, potentially creating large plumes. The use of a conceptual site model (CSM) to define risks posed by specific PFASs to potential receptors is considered essential. Granular activated carbon (GAC) is commonly used as part of interim remedial measures to treat PFASs present in water. Many alternative treatment technologies are being adapted for PFASs or ingenious solutions developed. The diversity of PFASs commonly associated with use of multiple PFASs in commercial products is not commonly assessed. Remedial technologies, which are adsorptive or destructive, are considered for both soils and waters with challenges to their commercial application outlined. Biological approaches to treat PFASs report biotransformation which creates persistent PFAAs, no PFASs can biodegrade. Water treatment technologies applied ex situ could be used in a treatment train approach, for example, to concentrate PFASs and then destroy them on‐site. Dynamic groundwater recirculation can greatly enhance contaminant mass removal via groundwater pumping. This review of technologies for remediation of PFASs describes that:
GAC may be effective for removal of long‐chain PFAAs, but does not perform well on short‐chain PFAAs and its use for removal of precursors is reported to be less effective;
Anion‐exchange resins can remove a wider array of long‐ and short‐chain PFAAs, but struggle to treat the shortest chain PFAAs and removal of most PFAA precursors has not been evaluated;
Ozofractionation has been applied for PFASs at full scale and shown to be effective for removal of total PFASs;
Chemical oxidation has been demonstrated to be potentially applicable for some PFAAs, but when applied in situ there is concern over the formation of shorter chain PFAAs and ongoing rebound from sorbed precursors;
Electrochemical oxidation is evolving as a destructive technology for many PFASs, but can create undesirable by‐products such as perchlorate and bromate;
Sonolysis has been demonstrated as a potential destructive technology in the laboratory but there are significant challenges when considering scale up;
Soils stabilization approaches are evolving and have been used at full scale but performance need to be assessed usin...
Coefficients of friction of wheat for grain-on-grain and on galvanized corrugated steel sheet were investigated using a modified direct shear apparatus. Tests were conducted under a normal pressure of 20.7 kPa using soft red winter wheat at a moisture content of 11.2% (w.b.) and an uncompressed bulk density of 740 kg/m 3. Three consolidation procedures and three methods of deposition of grain in the test chamber were used. Test results of grain-on-grain friction showed that consolidation procedure markedly influenced the force-displacement relationship, while its influence on the coefficients of friction were small. Shearing to peak strength as a consolidation method erased all effects of loading history and resulted in the highest values of the coefficient of friction. Grain-on-grain coefficients of friction were in a range from 0.47 + 0.007 to 0.56 + 0.004 depending on the method of grain deposition. Friction on two dimensionally different samples of corrugated steel sheet was examined using three methods of grain deposition. Corrugation depths were 13 mm on both samples, while their periods were 67.5 mm (short) and 104 mm (long). Coefficients of friction on the short-period corrugated samples were in a range from 0.42 + 0.0 to 0.46 + 0.004 and were significantly higher (a = 5%) than those on the long-period corrugated sample, which ranged from 0.36 + 0.003 to 0.39 +0.003. The method of grain deposition significantly (a = 5%) influenced the coefficients of friction of wheat on both types of corrugated steel sheet.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.