Context. Absorption-line systems detected in quasar spectra can be used to compare the value of the fine-structure constant, α, measured today on Earth with its value in distant galaxies. In recent years, some evidence has emerged of small temporal and also spatial variations in α on cosmological scales. These variations may reach a fractional level of ≈10 ppm (parts per million). Aims. To test these claims we are conducting a Large Program of observations with the Very Large Telescope's Ultraviolet and Visual Echelle Spectrograph (UVES), and are obtaining high-resolution (R ≈ 60 000) and high signal-to-noise ratio (S /N ≈ 100) UVES spectra calibrated specifically for this purpose. Here we analyse the first complete quasar spectrum from this programme, that of HE 2217−2818. Methods. We applied the many multiplet method to measure α in five absorption systems towards this quasar: z abs = 0.7866, 0.9424, 1.5558, 1.6279 , and 1.6919. Results. The most precise result is obtained for the absorber at z abs = 1.6919 where 3 Fe  transitions and Al  λ1670 have high S/N and provide a wide range of sensitivities to α. The absorption profile is complex with several very narrow features, and it requires 32 velocity components to be fitted to the data. We also conducted a range of tests to estimate the systematic error budget. Our final result for the relative variation in α in this system is ∆α/α = +1.3 ± 2.4 stat ± 1.0 sys ppm. This is one of the tightest current bounds on α-variation from an individual absorber. A second, separate approach to the data reduction, calibration, and analysis of this system yielded a slightly different result of −3.8 ± 2.1 stat ppm, possibly suggesting a larger systematic error component than our tests indicated. This approach used an additional 3 Fe  transitions, parts of which were masked due to contamination by telluric features. Restricting this analysis to the Fe  transitions alone and using a modified absorption profile model gave a result that is consistent with the first approach, ∆α/α = +1.1 ± 2.6 stat ppm. The four other absorbers have simpler absorption profiles, with fewer and broader features, and offer transitions with a narrower range of sensitivities to α. They therefore provide looser bounds on ∆α/α at the > ∼ 10 ppm precision level. Conclusions. The absorbers towards quasar HE 2217−2818 reveal no evidence of any variation in α at the 3-ppm precision level (1σ confidence). If the recently reported 10-ppm dipolar variation in α across the sky is correct, the expectation at this sky position is (3.2−5.4) ± 1.7 ppm depending on dipole model used. Our constraint of ∆α/α = +1.3 ± 2.4 stat ± 1.0 sys ppm is not inconsistent with this expectation.

Aims. Abundances of the Mg isotopes 24 Mg, 25 Mg, and 26 Mg can be used to test models of chemical enrichment of interstellar/intergalactic gas clouds. Additionally, because the position of the Mg ii λλ2796, 2803 Å lines is often taken as a reference in computations of possible changes of the fine-structure constant α, it should be clarified to which extent these lines are affected by isotopic shifts. Methods. We use a high-resolution spectrum (pixel size ≈1.3 km s −1 ) of the quasar HE0001-2340 observed with the UVES/VLT to measure Mg isotope abundances in the intervening absorption-line systems at high redshifts. Line profiles are prepared taking into account possible shifts between the individual exposures. In the line-fitting procedure, the lines of each ion are treated independently. Because of the unique composition of the selected systems -the presence of several transitions of the same ion -we can test the local accuracy of the wavelength scale calibration, which is the main source of errors in the sub-pixel line position measurements. Results. In the system at z abs = 0.45, which is probably a fragment of the outflow caused by SN Ia explosion of highmetallicity white dwarf(s), we measured velocity shifts of Mg ii and In the systems at z abs = 1.58 and z abs = 1.65 enriched by AGB-stars we find only upper limits on the content of heavy Mg isotopes ( 25 Mg+ 26 Mg)/ 24 Mg < ∼ 0.7 and ( 25 Mg+ 26 Mg)/ 24 Mg < ∼ 2.6, respectively. At z abs = 1.58, we also put a strong constraint on a putative variation of α: Δα/α = (−1.5 ± 2.6) × 10 −6 , which is one of the most stringent limits obtained from optical spectra of QSOs. We reveal that the wavelength calibration in the range above 7500 Å is subject to systematic wavelength-dependent drifts.

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Abstract. The Single Ion Differential α Measurement (SIDAM) method for measuring ∆α/α and its figures of merit are illustrated together with the results produced by means of Fe ii absorption lines of QSO intervening systems. The method provides ∆α/α = −0.12 ± 1.79 ppm (parts-per-million) at z abs = 1.15 towards HE 0515-4414 and ∆α/α = 5.66 ± 2.67 ppm at z abs = 1.84 towards Q 1101-264, which are so far the most accurate measurements for single systems. SIDAM analysis for 3 systems from the Chand et al. (2004) sample provides inconsistent results which we interpret as due to calibration errors of the Chand et al. data at the level ≈ 10 ppm. In one system evidence for photo-ionization Doppler shift between Mg ii and Fe ii lines is found. This evidence has important bearings on the Many Multiplet method where the signal for ∆α/α variability is carried mainly by systems involving Mg ii absorbers. Some correlations are also found in the Murphy et al. sample which suggest larger errors than previously reported. Thus, we consider unlikely that both the Chand et al. and Murphy et al. datasets could provide an estimate of ∆α/α with an accuracy at the level of 1 ppm. A new spectrograph like the ESPRESSO project will be crucial to make progress in the astronomical determination of ∆α/α .