Reaction of [MoCI4(NNMePh)] with ( B u ~~N ) ~[ M o ~O ~] yields a co-ordination complex with the hexanuclear oxomolybdate core, ( B u ~~N ) ~[ M o & ~( NNMePh)]; the reaction is general with appropriate precursors in providing a ready entry into the class of co-ordination compounds of the types [Mo5018(ML)]* and [W5018(ML)]*, with M = Mo or W and L = NNR2, NR, or N.
Mercury(II) and Methylmercury(II) Complexes of Novel Sterically Hindered Thiolates: 13C and 199Hg NMR Studies and the Crystal and Molecular Structures of [MeHg(SC6H2-2,4,6-Pr'3) ], [Hg(SC6H4-2-SiMe3)2], [Hg(2-SC5H3N-3-SiMe3)2], and [Hg|<2-SC6H4)2SiMe2|]2
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