Selective wetting-induced micro-electrode patterning is used to fabricate flexible micro-supercapacitors (mSCs). The resulting mSCs exhibit high performance, mechanical stability, stable cycle life, and hold great promise for facile integration into flexible devices requiring on-chip energy storage.
Materials which induce molecular motion without external input offer unique opportunities for spatial manipulation of molecules. Here, we present the use of polyacrylamide hydrogel films containing built-in chemical gradients (enthalpic gradients) to direct molecular transport. Using a cationic tertiary amine gradient, anionic molecules were directionally transported up to several millimeters. A 40-fold concentration of anionic molecules dosed in aerosol form on a substrate to a small region at the center of a radially symmetric cationic gradient was observed. The separation of mixtures of charged dye molecules was demonstrated using a boronic acid-to-cationic gradient where one molecule was attracted to the boronic acid end of the gradient, and the other to the cationic end of the gradient. Theoretical and computational analysis provides a quantitative description of such anisotropic molecular transport, and reveals that the gradient-imposed drift velocity is in the range of hundreds of nanometers per second, comparable to the transport velocities of biomolecular motors. This general concept of enthalpy gradient-directed molecular transport should enable the autonomous processing of a diversity of chemical species.
Fiber electrodes provide interesting opportunities for energy storage by providing both mechanical flexibility and the opportunity to impart multifunctionality to fabrics. We show here carbon nanotube (CNT)-embedded agarose gel composite fiber electrodes, with a diameter of ∼120 μm, consisting of 60 wt % CNTs that can serve as the basis for flexible and wearable fiber microsupercapacitors (mSCs). Via an extrusion process, CNT bundles are induced to align in an agarose filament matrix. Due to the shear alignment of the CNT bundles, the dehydrated filaments have an electrical conductivity as high as 8.3 S cm. The composite fiber electrodes are mechanically stable, enabling formation of twisted two-ply fiber mSCs integrated with a solid electrolyte. The fiber mSC shows a high capacitance (∼1.2 F cm), good rate retention (∼90%) at discharge current densities ranging from 5.1 to 38 mA cm, long cycle life under repeated charging/discharging (10% fade after 10 000 cycles) and good performance after at least 1000 cycles of deformation, with a radius of curvature of 12.3 mm (90° bend). After being coated with a thin layer of poly(dimethylsiloxane), the fiber mSCs could be cycled over 10 000 times under water. Impedance studies indicate that the superior performance is due to the high electrical conductivity along the aligned CNTs and the large electrode surface area that is accessible through the ion-conducting agarose.
We review the recent progress in the emerging area of devices and circuits operating on the basis of ionic currents. These devices operate at the intersection of electrochemistry, electronics, and microfluidics, and their potential applications are inspired by essential biological processes such as neural transmission. Ionic current rectification has been demonstrated in diode-like devices containing electrolyte solutions, hydrogel, or hydrated nanofilms. More complex functions have been realized in ionic current based transistors, solar cells, and switching memory devices. Microfluidic channels and networks-an intrinsic component of the ionic devices-could play the role of wires and circuits in conventional electronics.
We report a general diffusion based
method to form micrometer-scale
lateral chemical gradients in polymer brushes via selective alkylation.
A quaternized brush gradient is derived from a concentration gradient
of alkylating agent formed by diffusion in permeable media around
a microchannel carrying the alkylating agent. Polymer brushes containing
both charge and aromatic gradients are formed using the alkylating
agents, methyl iodide and benzyl bromide, respectively. The gradients
are quantitatively characterized by confocal Raman spectroscopy and
qualitatively by fluorescence microscopy. The length and gradient
strength can be controlled by varying the diffusion time, concentrations,
and solvents of the alkylating agent solutions. This microfluidic
brush gradient generation method enables formation of 2-D chemical
potential gradients with a diversity of shapes.
Graphene composite microwires with good electrical conductivities are formed by extrusion of a graphene oxide–agarose suspension followed by drying and reduction of graphene oxide to graphene.
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