Majority of dynamic nuclear polarization (DNP) experiments have been requiring helium cryogenics and strong magnetic fields for a high degree of nuclear polarization. In this work, we instead demonstrate an optical hyperpolarization of naturally abundant 13C nuclei in a diamond crystal at a low magnetic field and the room temperature. It exploits continuous laser irradiation for polarizing electronic spins of nitrogen vacancy centers and microwave irradiation for transferring the electronic polarization to 13C nuclear spins. We have studied the dependence of 13C polarization on laser and microwave powers. For the first time, a triplet structure corresponding to the 14N hyperfine splitting has been observed in the 13C polarization spectrum. By simultaneously exciting three microwave frequencies at the peaks of the triplet, we have achieved 13C bulk polarization of 0.113 %, leading to an enhancement of 90,000 over the thermal polarization at 17.6 mT. We believe that the multi-tone irradiation can be extended to further enhance the 13C polarization at a low magnetic field.
This paper presents the topology of a novel approach to magnetic communication using a differential magnetic induction (MI)-based receiver and a differential MI receiving sensor. In this paper, a differential MI sensor based on two ferromagnetic cores is proposed as a receiving sensor, unlike the air coiltype MI sensor in the conventional search coil sensor concept. This differential MI sensor has the advantages of ultra-high sensitivity characteristics of the pT/√Hz level, which can detect weak magnetic fields in magnetic communication; moreover, the sensor is smaller than a conventional air coil MI sensor. The proposed differential MI sensor contributes to improving sensor performance by increasing its signal-to-noise ratio. The design and fabrication of the proposed MI sensor were based on a printed circuit board (PCB). The pickup coil of the PCB-based MI sensor directly wound the pickup coil onto a ferromagnetic core composed of Ni-Zn ferrite material. To analyze the key factors that affected the performance of the receiver, the magnetic field-to-voltage conversion ratio (MVCR) and equivalent magnetic spectral density measurements of the proposed PCB-based MI sensor were performed. Wireless digital communication using quadrature phase shift keying (QPSK), which is less sensitive to noise and has a high data rate, was used to evaluate the proposed MI-based receiver. The transmitted and received waveforms were compared to confirm that the transmitted digital data were accurately received as a result of the final demodulation of the receiver. Additionally, several performance metrics, such as constellation and error vector magnitude, were measured. The results of the comprehensive analysis confirmed the applicability of the proposed differential MI-based receiver to a magnetic field.
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