Biological systems derive diverse functions from the self-assembly of multiple distinct products from the same molecular precursors. Similar effects have been shown in self-assembled coordination cages and metal-organic frameworks. Little...
The only reported synthesis of a [n]-azacubane, 1,4-diazacubane, on re-examination revealed a disordered piperazine that constitutes the previously reported Ni2+ Kagome metal organic framework (MOF).
The interplay of many factors influences the outcomes of self-assembly reactions. Using an acetylene-appended quaterpyridine ligand we show that both the size of metal ion and the presence of steric...
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