An attempt to degrade volatile organic compounds (VOCs) and sterilize air simultaneously is highly desirable to improve indoor air quality. With the help of deep ultraviolet (UVC) lighting, harmful bacteria that exists in the air can be destroyed. Thus, a new photocatalytic substance that can break down VOCs under UVC irradiation is required. Here, we demonstrate the photocatalytic activity of β-Ga2O3 nanostructures, synthesized via the solvothermal method for removing formaldehyde (HCHO) under deep ultraviolet irradiation. The Raman and XRD results indicated that as-synthesized nanostructures showed β-crystalline phase with a monoclinic structure. The photoluminescence spectrum exhibited a broad and strong green emission peak at 510 nm, which was likely attributed to a considerable amount of oxygen and gallium vacancies formed during the calcinating process. The photocatalytic efficiency for decomposing HCHO at room temperature under deep ultraviolet irradiation (278 nm) of the synthesized β-Ga2O3 nanoparticles is higher than that of the β-Ga2O3 nanorods. Both nanoparticles and nanorods obeyed the pseudo-first-order Langmuir-Hinshelwood kinetic model with a degradation rate constant of 0.057 and 0.033 min−1, corresponding to the efficiency of 82% and 62% in the formaldehyde removal, respectively.
Three types of SnO/SnO2 nanocomposites with different component ratios were synthesized using a simple hydrothermal process. Three samples, S1, S2, and S3, were produced by optimizing the occupied volume inside the Teflon flask, and are referred to as SnO2 rich, intermediate level, and SnO rich, respectively. In terms of degradation of malachite green under visible light, the photocatalytic activity of the S2 sample outperforms the other two samples and pure SnO by 30 %. It is attributed to the fact that the S2 sample has the most heterojunction between p‐type SnO and n‐type SnO2 of the three samples because the formation of p‐type SnO and n‐type SnO2 heterojunction in S2 prevents photogenerated electron‐hole recombination. By comparing S1 and S3 samples, we figured out that Sn2+ doped into the SnO2 lattice acts as an electron trap, slowing the recombination process and increasing photocatalytic activity.
Crystalline structure and optoelectrical properties of silver-doped tin monoxide thin films with different dopant concentrations prepared by DC magnetron sputtering are investigated. The X-ray diffraction patterns reveal that the tetragonal SnO phase exhibits preferred orientations along (101) and (110) planes. Our results indicate that replacing Sn 2+ in the SnO lattice with Ag + ions produces smaller-sized crystallites, which may lead to enhanced carrier scattering at grain boundaries. This causes a deterioration in the carrier mobility, even though the carrier concentration improves by two orders of magnitude due to doping. In addition, the Agdoped SnO thin films show a p-type semiconductor behavior, with a direct optical gap and decreasing transmittance with increasing Ag dopant concentration.
The sun provides a plentiful and inexpensive source of carbon-neutral energy that has yet to be fully utilized. This is a major driving force behind the development of organic photovoltaic (OPV) materials and devices, which are expected to offer benefits such as low cost, flexibility, and widespread availability. For the photovoltaic performance enhancement of the inverted ZnO-nanorods (NR)/organic hybrid solar cells with poly(3-exylthiophene):(6,6)-phenyl-C61-butyric-acid-methylester (P3HT:PCBM) and poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT:PSS) active layers, gold nanoparticles (Au-NPs) were introduced into the interface between indium-thin-oxide cathode layer and ZnO cathode buffer layer, and the efficiency improvement was observed. It's worth noting that adding Au NPs had both a positive and negative impact on device performance. Au NPs were shown to be advantageous to localized surface plasmon resonance (LSPs) in the coupling of dispersed light from ZnO NRs in order to extend the light's path length in the absorbing medium. Although the light absorption in the active layer could be enhanced, Au NPs might also act as recombination centers within the active layer. To avoid this adverse effect, Au NPs are covered by the ZnO seeded layer to prevent Au NPs from direct contact with the active layer. The dominant surface plasmonic effect of Au NPs increased the photoelectric conversion efficiency from 2.4% to 3.8%.
Stack and composite are the two ways of hybridization between gold nanoparticles (AuNPs) and reduced graphene oxide (rGO) which have been fabricated and tested the ability to detect NH3 gas at room temperature. The device based on the rGO-AuNP composite structure exhibited the highest response and the fastest response and recovery time compared to stack and bare rGO. The red shift of a resonant peak in the absorption spectra and the negative shift in the binding energy of 4f5/2 peak indicated that the remarkable NH3 gas-sensing properties of this composite are mainly attributed to a chemical bonding formed between AuNPs and rGO at the defective sites. This type of interaction facilitates the electron transfer from the defect states to the AuNP surface wherein it easily reacts with the oxygen molecules in the atmosphere to create oxygen absorbents. Consequently, NH3 not only reacts with sp3-hybridized atoms but also reacts primarily with oxygen absorbents on the surface of AuNPs, resulting in a better sensing behavior of composite samples.
Nano-Ag/PEDOT-PSS films were prepared by spin-coating technique. SEM surface morphology, Raman spectra and gas sensing of methanol, humidity and NH3 were studied. The obtained results showed that the resistance of Ag/PEDOT:PSS sheets exposed to gases related to the generation of electrons from the gases adsorption that eliminated holes as the major carriers in PEDOT:PSS. For NH3 gas the largest change of the resistance of Ag/PEDOT:PSS was observed. The less sensitivity of humidity and ethanol sensing was explained due to less dedoping reaction between H2O and ethanol vapor with Ag/PEDOT:PSS, respectively. This suggests a potential application of the nano-Ag/PEDOT-PSS sensors for the selective monitoring NH3 gas in environment.
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