Pyrophyllite (Al2Si4O10(OH)2) is a phyllosilicate often associated with quartz, mica, kaolinite, epidote, and rutile minerals. In its pure state, pyrophyllite exhibits unique properties such as low thermal and electrical conductivity, high refractive behavior, low expansion coefficient, chemical inertness, and high resistance to corrosion by molten metals and gases. These properties make it desirable in different industries such as refractory; ceramic, fiberglass, and cosmetic industries; as filler in the paper, plastic, paint, and pesticide industries; as soil conditioner in the fertilizer industry; and as a dusting agent in the rubber and roofing industries. Pyrophyllite can also serve as an economical alternative in many industrial applications to different minerals as kaolinite, talc, and feldspar. To increase its market value, pyrophyllite must have high alumina (Al2O3) content, remain free of any impurities, and possess as much whiteness as possible. This paper presented a review of pyrophyllite’s industrial applications, its important exploitable properties, and the specifications required for its use in industry. It also presents the most effective and economical techniques for enriching low-grade pyrophyllite ores to make them suitable for various industrial applications.

The Kingdom of Saudi Arabia covers an area of approximately 2 million km2 and is rich in natural resources that are necessary for industrial development. The estimated mineral wealth beneath the Kingdom’s soil is approximately USD 1.33 trillion, as reported by the Ministry of Industry and Mineral Resources. The Kingdom’s vision for 2030 is to develop the mining sector to become the third pillar of the domestic economy. Therefore, exploration and mining activities are expected to accelerate over the next decade, which will lead to increased waste production. New executive regulations issued in January 2021 contain several sustainable elements related to the environment, social responsibility, and occupational health and safety. Therefore, this study aims to promote an example of sustainable mining activities in the Kingdom that could be adapted to meet the regulatory requirements. Cemented paste backfill samples of varying composition were made with waste materials from a Saudi copper mine for re-injection into underground mining cavities to minimize waste exposure to the environment. The samples were tested for unconfined compressive strength (UCS) after 7, 14, 28, 56, and 90 days of curing. Results from a statistically designed experiment technique show that the samples developed sufficient strength to be used in mine backfilling applications. Strong negative relationships were detected between the UCS and the water-to-binder ratio. There is strong potential for mine backfill technology to be applied to a wide range of Saudi Arabian mines to enhance the sustainability of the mining sector.

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The comminution of ores consumes a high portion of energy. Therefore, different pretreatment methods of ores prior to their comminution are considered to reduce this energy. However, the results of pretreatment methods and their technological development are scattered in literature. Hence, this paper aims at collating the different ore pretreatment methods with their applications and results from published articles, conference proceedings, and verified reports. It was found that pretreatment methods include thermal (via oven, microwave, or radiofrequency), chemical additive, electric, magnetic, ultrasonic, and bio-milling. Results showed that the chemical pretreatment method has been used at an industrial scale since 1930, mainly in cement production. The microwave pretreatment results showed positive improvements at pilot scale mining applications in 2017. The results of ore pretreatment using electric and ultrasonic methods showed up to 24% and 66% improvement in energy consumption, respectively. The former and the latter have been piloted for gold and carbonate ore, respectively. Findings also showed that magnetic, radiofrequency, and bio-milling methods have not led to significant reductions in comminution energy. Based on energy reduction, safety, costs, stage of application, and downstream benefits, microwave and electrical pretreatment methods may be focused for applications in the mining industry.