[reaction: see text] The diphenylamino group is an effective handle for electropolymerization to give electron donor-acceptor conjugated polymers. In addition, interesting electrochromic and photoresponsive behavior of 13 has been investigated.

We study the surface plasmon modes in a silver double-nanowire system by employing the eigenmode analysis approach based on the finite element method. Calculated dispersion relations, surface charge distributions, field patterns and propagation lengths of ten lowest energy plasmon modes in the system are presented. These ten modes are categorized into three groups because they are found to originate from the monopole-monopole, dipole-dipole and quadrupole-quadrupole hybridizations between the two wires, respectively. Interestingly, in addition to the well studied gap mode (mode 1), the other mode from group 1 which is a symmetrically coupled charge mode (mode 2) is found to have a larger group velocity and a longer propagation length than mode 1, suggesting mode 2 to be another potential signal transporter for plasmonic circuits. Scenarios to efficiently excite (inject) group 1 modes in the two-wire system and also to convert mode 2 (mode 1) to mode 1 (mode 2) are demonstrated by numerical simulations.

Tris(2-((pyrid-2-ylmethyl)uredio)ethyl)amine (2) and its perchlorate salt, 2.HClO(4), bind with Li+ in nitromethane in a 1:1 fashion. The stability constants of K(Li+) and K(H)(Li+) were found to be 112 +/- 25 and 130 +/- 30 M(-)(1) in CD(3)NO(2), respectively. Formation of the 1:1 complexes were further evidenced by electrospray ionization mass spectrometry (ESI-MS). The slight increase, or at least the same order of magnitude, of K(H)(Li+) compared to K(Li+) points to a remarkable preorganization of the protonated podand in 2.HClO(4), that essentially overcomes the increased Columbic repulsion occurring on complexation to Li+.