Flexible porous membranes have attracted increasing scientific interest due to their wide applications in flexible electronics, energy storage devices, sensors, and bioscaffolds. Here, inspired by nature, we develop a facile and scalable top-down approach for fabricating a superflexible, biocompatible, biodegradable three-dimensional (3D) porous membrane directly from natural wood (coded as flexible wood membrane) via a one-step chemical treatment. The superflexibility is attributed to both physical and chemical changes of the natural wood, particularly formation of the wavy structure formed by simple delignification induced by partial removal of lignin/hemicellulose. The flexible wood membrane, which inherits its unique 3D porous structure with aligned cellulose nanofibers, biodegradability, and biocompatibility from natural wood, combined with the superflexibility imparted by a simple chemical treatment, holds great potential for a range of applications. As an example, we demonstrate the application of the flexible, breathable wood membrane as a 3D bioscaffold for cell growth.
Here we report the unparalleled performance of a novel acid hydrotrope, p-toluenesulfonic acid (p-TsOH), for the rapid and nearly-complete dissolution of wood lignin below the boiling temperature of water.
Developing advanced building materials with both excellent thermal insulating and optical properties to replace common glass (thermal conductivity of ∼1 W m −1 K −1 ) is highly desirable for energy-efficient applications. The recent development of transparent wood suggests a promising building material with many advantages, including high optical transmittance, tunable optical haze, and excellent thermal insulation. However, previous transparent wood materials generally have a high haze (typically greater than 40%), which is a major obstacle for their practical application in the replacement of glass. In this work, we fabricate a clear wood material with an optical transmittance as high as 90% and record-low haze of 10% using a delignification and polymer infiltration method. The significant removal of wood components results in a highly porous microstructure, much thinner wood cell walls, and large voids among the cellulose fibrils, which a polymer can easily enter, leading to the dense structure of the clear wood. The separated cellulose fibrils that result from the removal of the wood components dramatically weaken light scattering in the clear wood, which combined with the highly dense structure produces both high transmittance and extremely low haze. In addition, the clear wood exhibits an excellent thermal insulation property with a low thermal conductivity of 0.35 W m −1 K −1 (one-third of ordinary glass); thus, the application of clear wood can greatly improve the energy efficiency of buildings. The developed clear wood, combining excellent thermal insulating and optical properties, represents an attractive alternative to common glass toward energyefficient buildings.
Two lignin-containing cellulose nanofibril
(LCNF) samples, produced
from two unbleached kraft pulps with very different lignin contents,
were used to produce reinforced polyvinyl alcohol (PVA) hydrogels.
The effects of LCNF loading (0.25–2 wt %) and lignin content
on the rheological and mechanical properties of the reinforced hydrogels
were investigated. The 2 wt % LCNF-reinforced PVA hydrogels exhibited
up to a 17-fold increase in storage modulus and a 4-fold increase
in specific Young’s modulus over that of pure PVA hydrogel.
Both the mechanical and rheological properties of LCNF-reinforced
PVA hydrogels can be tuned by varying LCNF loading and LCNF lignin
content. During LCNF production, lignin reduced cellulose depolymerization,
resulting in LCNF with high aspect ratios that promoted entanglement
and physical bridging of the hydrogel network. Free lignin particles
generated during LCNF production acted as multifunctional nanospacers
that increased porosity of the hydrogels. Because LCNFs were produced
from unbleached chemical pulps, which have high yields and do not
require bleaching, this study provides a more sustainable approach
to utilize lignocelluloses to produce biomass-based hydrogels than
by methods using commercial bleached pulps.
TEMPO-oxidized cellulose nanofibrils (TOCNs) films cross-linked with different dosages of polyamide epichlorohydrin resin (PAE) show a great water-resistance and thermal stability.
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