Iron ore-carbon briquette is often used as the feed material in the production of sponge iron via coal-based direct reduction processes. In this article, an experimental and simulation study on the reduction behavior of a briquette that is made by hematite and devolatilized biochar fines under CO-CO 2 atmosphere was carried out. The reaction model was validated against the corresponding experimental measurements and observations. Modeling predictions and experimental results indicated that the CO-CO 2 atmosphere significantly influences the final reduction degree of the briquette. Increasing the reduction temperature did not increase the final reduction degree but was shown to increase the carbon that was consumed by the oxidative atmosphere. The influence of the CO-CO 2 atmosphere on the briquette reduction behavior was found to be insignificant in the early stage but became considerable in the later stage; near the time of the briquette reaching its maximum reduction degree, both iron oxide reduction and metallic iron re-oxidation were able to occur.
The application of carbon composite briquette (CCB) is considered to be an efficient method for achieving low-energy and low-CO2-emission blast furnace (BF) operations. In this research, a combined experimental and numerical study was conducted on the CCB reaction behavior in BF. The CCB used in this study had a composition of 20.10 wt.% carbon, 29.70 wt.% magnetite, 39.70 wt.% wüstite, and 1.57 wt.% metallic iron. Using the prepared CCB samples, isotherm reduction tests under a simulated BF atmosphere (CO-CO2-N2) were conducted and a reaction model was developed. Subsequently, the reaction behavior of CCB along the mid-radial solid descending path in an actual BF of 2500 m3 was analyzed by numerical simulations based on the experimental findings and the previous results of comprehensive BF modeling. The results of the experiments showed that the CCB model predictions agreed well with the experimental measurements. With respect to the BF, the results of the numerical simulations indicated that, along the path, before the CCB temperature reached 1000 K, the CCB was reduced by CO in the BF gas; when its temperature was in the range from 1000 to 1130 K, it underwent self-reduction and contributed both CO and CO2 to the BF gas; when its temperature was above 1130 K, it only presented carbon gasification. Moreover, these results also revealed that the reduction of iron oxide and the gasification of carbon inside the CCB proceeded under an uneven mode. The uneven radial distribution of the local reduction fraction and local carbon conversion were evident in the self-reducing stage of the CCB.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.