A dehydrogenative
annulation of 2-arylindazoles with maleimides
for the switchable synthesis of indazolo[2,3-a]pyrrolo[3,4-c]quinolinones or spiroindolo[1,2-b]indazole-11,3′-pyrrolidinones
is presented. Mechanistically, the formation of the title compounds
involves a Rh(III)-catalyzed C–H metalation of 2-arylindazole,
followed by maleimide insertion and intramolecular cyclization. Interestingly,
the selectivity to form the fused or spiro compounds could be switched
by resorting to different additives. The notable features of this
protocol include simple substrates and excellent atom economy and
regioselectivity.
A novel dual-band bi-directional reconfigurable antenna based on Koch patch is presented in this paper. By controlling the switches in the slots etched on the Koch patch, different far field bi-directional patterns at the dual-band around 60 GHz/80 GHz could be achieved. And full azimuthal coverage at this dual-band is possible by electronically controlling the switches in the slots of the patch.
The disposal process of iron-containing sludge often leads to secondary pollution. Pyrolysis of sludge appears to be less polluting than conventional methods. Herein, the heterogeneous photo-Fenton catalysts were prepared using sludge generated in the dyeing wastewater through a simple one-step pyrolysis route. The catalysts were characterized by XRD, FT-IR, XPS, EDS, BET, and SEM. The batch experiments for methyl orange (MO) degradation were performed to evaluate the efficiency and stability of the catalysts. Among the catalysts prepared, FeCN-300 exhibited the best degradation efficiency with 92% removal of the pollutant and good stability, with approximately 90% removal of the pollutant after five cycles. The •OH was identified as the dominant reactive species. This work provides a reasonable resource utilization of iron-containing sludge.
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