Recently, monolayer molybdenum disulphide (MoS2) has emerged as a promising and non–precious electrocatalyst for hydrogen evolution reaction. However, its performance is largely limited by the low density and poor reactivity of active sites within its basal plane. Here, we report that domain boundaries in the basal plane of monolayer MoS2 can greatly enhance its hydrogen evolution reaction performance by serving as active sites. Two types of effective domain boundaries, the 2H-2H domain boundaries and the 2H-1T phase boundaries, were investigated. Superior hydrogen evolution reaction catalytic activity, long-term stability and universality in both acidic and alkaline conditions were achieved based on a multi-hierarchy design of these two types of domain boundaries. We further demonstrate that such superior catalysts are feasible at a large scale by applying this multi-hierarchy design of domain boundaries to wafer-scale monolayer MoS2 films.
By using the constrained-phase quantum Monte Carlo method, we performed a systematic study of the ground state of the half-filled Hubbard model for a trilayer honeycomb lattice. We analyse the effect of the perpendicular electric field on the electronic structure, magnetic property and pairing correlations. It is found that antiferromagnetic fluctuations emerge with the perpendicular electric field, and the electronic correlation drives a d + id superconducting pairing to be dominant over other pairing patterns among various electric fields and interaction strengths. We also found that the d + id pairing correlation is greatly enhanced as the on-site Coulomb interaction is increased. Our intensive numerical results may unveil the nature of the recently observed superconductivity in rhombohedral trilayer graphene under an electric field.
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