Strong base and large size cation have been shown to accelerate the rate and the yield of Suzuki coupling of a sterically bulky boronic acid with halopyridines in DME for the synthesis of pyridylphenols.
Synthesis of Binucleating Ligands of Pyridylphenol. -The synthesis of pyridylphenol-type dinucleating tri-[cf. (III), (V)] and pentadentate ligands [cf. (VI)] by Pd-catalyzed cross-coupling reactions is reported. -(ZHANG,
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