The control of photoluminescence and absorption of lead halide perovskites plays a key role in their applications in micro- and nano-sized light emission devices and photodetectors. To date, the wavelength controls of lead halide perovskite microlasers are mostly realized by changing the halide mixture in solution. Herein, we report the postsynthetic and selective control of the optical properties of lead halide perovskites with conventional semiconductor technology. By selectively exposing a CHNHPbBr microstructure with chlorine in inductively coupled plasma, we find that the wavelengths of absorption, photoluminescence, and laser emissions of exposed structures are blue-shifted around 50 nm. Most importantly, the device characteristics such as the photoluminescence intensities and laser thresholds are well maintained during the reaction process. We believe our finding will significantly boost the practical applications of lead halide perovskite based optoelectronics.

Styrene Butadiene Styrene (SBS) polymer-modified asphalt binders have become widely used in asphalt pavement because of their advantages in high- and low-temperature performance and fatigue resistance. Asphalt pavement is inevitably exposed to sunlight and ultraviolet (UV) radiation during its construction and service life. However, consideration of the aging effect of UV radiation is still limited in current pavement design and evaluation systems. In order to evaluate the impact of UV radiation on the aging properties of SBS-modified asphalt binders, UV aging tests were performed on Rolling Thin Film Oven Test (RTFOT)-aged samples with different UV radiation intensities and aging times. Sixteen different groups of tests were conducted to compare the rheological properties and functional group characteristics of SBS-modified asphalt binders. Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR), FTIR, and SEM tests were conducted to evaluate the aging mechanisms in various UV aging conditions. The results found that UV radiation seriously destroys the network structure formed by the cross-linking effect in SBS-modified asphalt binders, which aggravates the degradation of SBS and results in a great change of rheological properties after UV aging. The nature of SBS-modified asphalt binder aging resulted from the degradation of SBS and the changes of asphalt binder base composition, which lead to the transformation of colloidal structure and the deterioration of asphalt binder performance. The tests also found that continuous UV radiation can increase shrinkage stress in the asphalt binder surface and leads to surface cracking of the asphalt binder.

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