Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are...

Luminescent metal−organic frameworks (MOFs) are of interest for sensing, theranostics, dosimetry, and other applications. The use of lanthanoids in MOF nodes allows for intrinsic metal-based luminescence. In this work, a facile route for modulating the photoluminescent and radioluminescent properties of Tb(III)-based MOFs is reported. By using Tb(III) cluster nodes as X-ray attenuators, and organic linkers with varying excited state energies as sensitizers, MOFs with metalbased, linker-based, and metal+linker-based photo-and radioluminescence are reported.

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Y-CU-45, an analogue of Zr-MOF-808, is synthesized for the first time. Several reaction conditions are tested demonstrating that two fluorinated modulators are required for a reproducible synthesis yielding high quality...