Vacuum insulation panels (VIPs) have a thermal resistance that is about a factor of 10 higher than that of equally thick conventional polystyrene boards. VIPs nowadays mostly consist of a load-bearing kernel of fumed silica. The kernel is evacuated to below 1 mbar and sealed in a highbarrier laminate, which consists of several layers of Al-coated polyethylene (PE) or polyethylene terephthalate (PET). The laminate is optimized for extremely low leakage rates for air and moisture and thus for a long service life, which is required especially for building applications. The evacuated kernel has a thermal conductivity of about 4 × 10 −3 W · m −1 · K −1 at room temperature, which results mainly from solid thermal conduction along the tenuous silica backbone. A U-value of 0.2 W · m −2 · K −1 results from a thickness of 2 cm. Thus slim, yet highly insulating façade constructions can be realized. As the kernel has nano-size pores, the gaseous thermal conductivity becomes noticeable only for pressures above 10 mbar. Only above 100 mbar the thermal conductivity doubles to about 8 × 10 −3 W · m −1 · K −1 , such a pressure could occur after several decades of usage in a middle European climate. These investigations revealed that the pressure increase is due to water vapor permeating the laminate itself, and to N 2 and O 2 , which tend to penetrate the VIP via the sealed edges. An extremely important innovation is the integration of a thermo-sensor into the VIP to nondestructively measure the thermal performance in situ. A successful "self-trial" was the integration of about 100 hand-made VIPs into the new ZAE-building in Würzburg. Afterwards, several other buildings were super-insulated using 1 1124 Fricke, Schwab, and HeinemannVIPs within a large joint R&D project initiated and coordinated by ZAE Bayern and funded by the Bavarian Ministry of Economics in Munich. These VIPs were manufactured commercially and integrated into floorings, the gable façade of an old building under protection, the roof and the facades of a terraced house as well as into an ultra-low-energy "passive house" and the slim balustrade of a hospital. The thermal reliability of these constructions was monitored using an infrared camera.
For vacuum insulation panels (VIPs) with fumed silica kernels and foils as cover, a calculation model is developed to predict the service life. It is defined as the period during which the thermal conductivity of the VIP has risen 50% due to infusion of air and moisture. Two panel sizes, 50 Â 50 Â 1 cm 3 and 100 Â 100 Â 2 cm 3 are considered. For VIPs with laminated aluminum foils, calculated service lives of many decades are determined. For VIPs with aluminum-coated multilayer foils, shorter service lives still above 20 are calculated. This is due to the higher water vapor transmission through the Al-coated multilayer foils (compared to laminated Al foil) and the humidity-related increase in thermal conductivity. Overall, our model predicts service lives, which are large enough for applications of VIPs in buildings. An open question that remains is the long-term stability of the foil cover.
Vacuum insulation panels (VIPs) are distinguished by their outstandingly low thermal conductivity. In the evacuated state, the VIPs being examined in this study (which have fumed silica as a core material) have a thermal conductivity of 4 10 3 W/(m K). Gases (N2, O2, H2O,...), which penetrate the foil cover cause an increase in pressure and water content and hence, an increase in the thermal conductivity. To determine these increases, VIPs have been manufactured with laminated aluminum foils (AlF) and aluminum-coated multilayer foils (MFs). The pressure and mass increases are determined at various temperatures, humidity, and with various panel formats. Large differences in the rates of pressure increases (1 -70 mbar/yr) and in the rates of mass increases (0.02-4 mass%/yr) are recorded, depending on the foil type, climatic conditions, and panel formats. From these measurements, the air and vapor transmission rates of the foil covers and their dependence on temperature, relative humidity, and panel size are derived. Using these gas transmission rates, it is possible to estimate which pressure increases are to be expected for panel formats and climatic conditions occurring in building applications. With laminated Al foils and selected Al-coated multilayer foils, rates of pressure increases below 1-2 mbar/yr are achieved. The rates of mass increase for typical climatic conditions for laminated Al foils are significantly below 0.1 mass%/yr, while with Al-coated multilayer foils, depending on the foil quality, mass increases per time of up to 1 mass%/yr are recorded. Increases in gas pressure per time of 1 -2 mbar/yr lead to relatively small increases in thermal conductivity, allowing applications in the construction sector, where service lives of several decades are required. With respect to the humidity-related increase in thermal conductivity, one has to know the climatic conditions, which have a strong influence on the increase in mass, and, above all, the precise dependence of the thermal conductivity on the humidity in the VIP.
Convection experiments described by Tritton & Zarraga (1967) with electrolytically heated fluid layers were renewed in order to investigate the reported phenomena, which were hitherto unknown and which contradicted a corresponding theory of Roberts. While the apparatus was essentially unchanged, provisions were incorporated to study the possible influence of several flow and equipment parameters on the convection pattern. With the exception of the temperature dependence of the electric conductivity, the new experiments displayed no essential effects of the convection parameters. Experiments with shallow fluid layers revealed a clear co-orientation of the convection flows with the electric current and a strong time dependence of the hexagonal patterns. Experiments with deeper fluid layers exhibited a considerably diminished time and direction dependence of the convection flow, and a significant reduction of the dilation of the cells. Based on these observations, it is concluded that no drastic differences between theory and experiments, and between internal and external heating, exist, provided the heating is sufficiently uniform.
The influence of moisture in vacuum insulation panels (VIPs), with fumed silica kernels, on their thermal conductivity has been investigated. The VIPs are produced with different water contents. The thermal conductivities at different water contents are measured under stationary conditions in a hot-plate apparatus with an average temperature of 10°C (plate temperatures are 0 and 20°C). The increase in thermal conductivity is approximately proportional to the water content. The increase is ≈0.5 × 10 -3 W/(m K) per mass% of water. For typical middle European climate, a maximum moisture content of ≈6 mass% can be expected, which corresponds to a maximum increase of thermal conductivity of ≈3 × 10 -3 W/(m K) for VIPs with fumed silica kernels.
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