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Catalysts 16NixFe/Al2O3(xis 0, 1, 2, 4, 6, 8) were prepared by incipient wetness impregnation method and the catalytic performance for the production of synthetic natural gas (SNG) from CO hydrogenation in slurry-bed reactor were studied. The catalysts were characterized by BET, XRD, UV-Vis DRS, H2-TPR, CO-TPD, and XPS, and the results showed that the introduction of iron improved the dispersion of Ni species, weakened the interaction between Ni species and support and decreased the reduction temperature and that catalyst formed Ni-Fe alloy when the content of iron exceeded 2%. Experimental results revealed that the addition of iron to the catalyst can effectively improve the catalytic performance of low-temperature CO methanation. Catalyst 16Ni4Fe/Al2O3with the iron content of 4% exhibited the best catalytic performance, the conversion of CO and the yield of CH4reached 97.2% and 84.9%, respectively, and the high catalytic performance of Ni-Fe catalyst was related to the property of formed Ni-Fe alloy. Further increase of iron content led to enhancing the water gas shift reaction.

The high temperature anhydrous interaction between Cu(acac)2 and NH4Y was investigated to prepare a chlorine-free CuY catalyst for the oxidative carbonylation of methanol to DMC. The Cu/NH4Y-400 catalyst shows superior catalytic activity.

Multi-wedge synchronous rolling by cross-wedge rolling is one of the most advanced methods that can form rolling railway axis. Its rolling quality mainly lies on inner transversal stress and shearing stress of rolling workpiece. In this paper, based on the rotated theory of multi-wedge rolling, through using Ansys/Ls-Dyna FEM software, multi-wedge synchronous rolling railway axis by cross-wedge rolling is simulated. It has been systemically researched that technical parameters effect transversal stress and shearing stress. In the meantime, the calculating model is verified by experiment. Through this study, It is obtained that the law of technical parameters effect on rolling railway axis by multi-wedge synchronous cross-wedge rolling. These research conclusions can provide scientific basis for rolling railway axis by multi-wedge synchronous cross-wedge rolling and rolling better quality.