In situ surfactant-free emulsion polymerization can help avoid the utilization of harmful co-solvents and surfactants in the preparation of waterborne poly(urethane-acrylate) (WPUA) nanoemulsion, but the solid content is extremely limited, which will affect the drying rate and film-forming properties. The utilization of polymerizable macrosurfactants can overcome the above problems. However, the research on cationic polymerizable macrosurfactants is extremely scarce. In this work, cationic dimethylaminoethyl methacrylate-b-alkyl methacrylates block copolymers (PDM-b-PRMA) with terminal double bonds and different hydrophobic side chain (HSC) lengths were fabricated via catalytic chain transfer polymerization (CCTP). HSC length of PDM-b-PRMA played an important role in the phase inversion, morphology, rheological behavior of WPUA nanoemulsions, as well as the comprehensive performance of WPUA/PDM-b-PRMA films. Polymerizable PDM-b-PBMA macrosurfactant had smaller molecular weight, lower surface tension and colloidal size than the random copolymer (PDM-co-PBMA) by traditional free radical polymerization. It was easy for PDM-b-PRMA to orientedly assemble at the oil/water interface and provide better emulsifying ability when the carbon number of HSC was four. Compared with WPUA/PDM-co-PBMA, WPUA/PDM-b-PBMA had a smaller particle size, stability and better film-forming properties. This work elucidated the mechanisms of HSC length in the fabrication of cationic PDM-b-PRMA and provides a novel strategy to prepare cationic WPUA of high performance.2 of 17 have [17] developed a poly(urethane-acrylate) (PUA) with enhanced ionic conductivity and excellent mechanical properties.PUA comprised the advantages of both polyurethane and acrylic polymers, and has been widely used in coatings, adhesives, and surface treatments [17,18]. Up to date, researchers have developed the focus of PUA research into waterborne poly(urethane-acrylate) (WPUA) to reduce the utilization of organic solvents, including anionic, cationic, and nonionic WPUA [19,20]. Heretofore, anionic WPUA has been extensively investigated [21][22][23][24][25]. Fei et al. [26] have used pentaerythritol triacrylate and hydroxyethyl acrylate as cross-linker to fabricate WPUA microemulsions, which was able to increase the mechanical properties and water resistance of cellulose fiber-based paper. Hou et al. [27] have prepared a waterborne anionic alkoxysilane-terminated polyurethane dispersion, which exhibited mechanical properties and excellent freeze-thaw stability.Compared with anionic WPUA, cationic WPUA displays better adhesion to anionic substrates such as cellulose fiber paper, glass and leather, etc. [28][29][30]. However, investigations on cationic WPUA are relatively rare to date [31,32]. Sheng et al. [33] have obtained WPUA with long-chain hydrophobic alkyl structure by radical polymerization of stearyl acrylate with double bond end-capped WPU, which has been used for water repellents. Heretofore, several approaches have been adopted to prepare WPUA, such as phys...
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