The extraction of zinc from zinc sulfate solution was investigated, using 20% saponified D2EHPA as an extractant and 260 # sulfonate kerosene as a diluent. The solution was stirred for 8 min at phase ratio (V o /V a ) of ,0.1׃0.1 initial pH of 2.0 and stirring speed of 200 r/min. The results show that 75% zinc can be extracted from the zinc sulfate solution when the concentration of zinc is 18.7 g/L after being settled for 10 min. 88.60% zinc can be stripped by 196 g/L sulfuric acid, and zinc ion can be separated from ferric ion.
The electrochemistry behaviors of gold electrode in thiourea solution were studied by using electrochemical techniques, such as potentiodynamic, voltammogram and current step. A catalytical electrochemical-reduction mechanism was proposed to identify the anodic oxidation of gold in the thiourea solution. The results indicate that the decomposition of thiourea occurs when the electrode potential is higher than 640 mV. The addition of sulfurous acid presents a very positive effect on the anodic process of gold electrode. The anodic oxidation rate of gold is 5 times faster than that without sulfurous acid. The passivity of gold electrode is attributed to the accumulation of elemental sulfur on the surface of gold. The sulfurous acid reacts with the oxidation product ((SC(NH)N H2 )2) of thiourea, which can decrease the decomposition of thiourea and improves its stability.
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