Surface-enhanced Raman Scattering (SERS) of R6G has been observed in two different silver colloids in the presence of KBr. It was found in spherical nanoparticles with an average diameter of 10 ( 2 nm and in their photoinduced conversion products with sodium light irradiation, silver nanoprisms, with an average edge length of 70 ( 30 nm and thickness of about 10 ( 2 nm. The SERS intensity of R6G (4.5 × 10 -9 M) in the silver nanoprism colloid was 20× stronger than in the spherical nanoparticle colloid with the addition of KBr (0.05 M). Comparing the Raman signal intensity of water (55.5 M) and the SERS intensity of R6G (4.5 × 10 -9 M) in the same spectrum showed that the analytical enhancement factors (AEF) in the truncated silver nanoprism colloid and spherical nanoparticle colloid are about 1.6 × 10 5 and 8 × 10 3 , respectively. Monitoring the fluorescent intensity of R6G versus the concentration of R6G in two colloids in the absence of KBr displayed that the nanoprisms had better fluorescence quenching ability than the spherical nanoparticles by a factor of around 3. It implied that light irradiation not only converted the morphology of the spherical nanoparticles to nanoprisms, but also changed the surface character to have a higher affinity to the dye molecule. The surface enhancement factors (SEF) can also be calculated from AEF and the percentage of dye molecules adsorbed on the surface in the presence of KBr. The SEF of the nanoprism and spherical nanoparticle colloids are about 3.2 × 10 5 and 9 × 10 3 , respectively. The UV-vis-NIR spectra and TEM images show that the spherical nanoparticles remained dispersed, while the nanoprisms were sculptured by the bromide ions after the addition of KBr.