Accelerated carbonation of basic oxygen furnace slag (BOFS) coupled with cold-rolling wastewater (CRW) was performed in a rotating packed bed (RPB) as a promising process for both CO 2 fixation and wastewater treatment. The maximum achievable capture capacity (MACC) via leaching and carbonation processes for BOFS in an RPB was systematically determined throughout this study. The leaching behavior of various metal ions from the BOFS into the CRW was investigated by a kinetic model. In addition, quantitative X-ray diffraction (QXRD) using the Rietveld method was carried out to determine the process chemistry of carbonation of BOFS with CRW in an RPB. According to the QXRD results, the major mineral phases reacting with CO 2 in BOFS were Ca(OH) 2 , Ca 2 (HSiO 4 )(OH), CaSiO 3 , and Ca 2 Fe 1.04 Al 0.986 O 5 . Meanwhile, the carbonation product was identified as calcite according to the observations of SEM, XEDS, and mappings. Furthermore, the MACC of the lab-scale RPB process was determined by balancing the carbonation conversion and energy consumption. In that case, the overall energy consumption, including grinding, pumping, stirring, and rotating processes, was estimated to be 707 kWh/t-CO 2 . It was thus concluded that CO 2 capture by accelerated carbonation of BOFS could be effectively and efficiently performed by coutilizing with CRW in an RPB.
As the number of World Heritage Sites (WHSs) is time-invariant or rarely changing in the short run, the panel data model reaches inconsistent estimates of the real effect of WHSs on tourist arrivals. This study adopts two alternative techniques, the fixed-effect vector decomposition (FEVD) approach and the two-stage, double fixedeffect (TSDFE) model, to revisit the WHS-tourism nexus. Based on China's provincial-level panel data over the 2000-2005 period, estimates using the fixed-effect panel data model show an insignificant impact of WHSs on tourist arrivals. Crucially, the empirical results obtained from both FEVD and TSDFE confirm a positive relationship between WHSs and international tourists in China. Moreover, cultural WHSs tend to exhibit a stronger tourism-enhancing effect than the natural WHSs. This study also highlights the importance of dealing with the time-invariant and/or rarely changing attributes in examining tourism demand.
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