Variability and vertical structure of optically thin veil clouds over the stratocumulus to cumulus transition (SCT) are investigated using spaceborne satellite observations. Optically thin veil clouds, defined as the low clouds with cloud base >1 km that do not fully attenuate Cloud‐Aerosol Lidar with Orthogonal Polarization (CALIOP) lidar signal, comprise ∼30% of the low clouds over the SCT. It is found that optically thin veil clouds are geometrically thin with cloud thickness ∼200 m and commonly reside in the upper boundary layer with average cloud base >1.5 km. Satellite observations reveal pronounced relationships between optically thin veil clouds, strong precipitation, deep planetary boundary layer (PBL) height, and low‐cloud droplet number concentration. The results are in agreement with the hypothesis that the low optical thickness of veil clouds over the SCT is contingent on the low‐cloud droplet number concentration caused by strong precipitation scavenging occurring in active cumulus, a process of which efficiency is strongly dependent on maximum condensate amount in updrafts and thus is highly constrained by planetary boundary layer height.
This study examines the temperature control of variability of tropical tropopause layer (TTL) cirrus clouds (i.e., clouds with bases higher than 14.5 km) by using 8 years (2006–2014) of observations from the Cloud‐Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) and Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC). It is found that the temporal variability of vertical structure of TTL cirrus cloud fraction averaged between 15°N and 15°S can be well explained by the vertical temperature gradient below ~17.5 km but by the local temperature above for both seasonal and interannual time scales. It is also found that the TTL cirrus cloud fraction at a given altitude is best correlated with the temperature at a higher altitude and this vertical displacement increases with a decrease of the cirrus altitude. It is shown that the TTL cirrus cloud fractions at all altitudes are significantly correlated with tropical cold point tropopause (CPT) temperature. The plausible mechanisms that might be responsible for the observed relations between TTL cirrus fraction and temperature‐based variables are discussed, which include ice particle sediments, cooling associated with wave propagations, change of atmospheric stability, and vertical gradient of water vapor mixing ratio. We further examine the spatial covariability of TTL total cirrus cloud fraction and CPT temperature for the interannual time scale. It is found that the El Niño–Southern Oscillation and quasi‐biennial oscillation are the leading factors in controlling the spatial variability of the TTL cirrus clouds and temperatures.
A simple micellar electrokinetic chromatographic method is described for simultaneous determination of digoxin and digitoxin. The simultaneous analysis of digoxin and digitoxin was performed in Tris buffer (10 mM; pH 9) with 90 mM sodium dodecyl sulfate and 10% isopropyl alcohol as an anionic surfactant and organic modifier. Under these conditions, good separation with high efficiency is achieved in short analysis times. Several parameters affecting the separation of the drugs were studied, including the pH and concentrations of the Tris buffer and sodium dodecyl sulfate. The linear range of the method for the determination of digoxin and digitoxin was over 0.01 -0.3 mg/mL; the detection limit (signal to noise ratio = 3; injection 3.5 kPa 3 s) was 4 and 6 lg/mL, respectively. Application of the proposed method to the determination of digoxin in commercial tablets and in injections proved to be feasible.
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