The second generation of ocean-color-analyzing instruments requires more accurate atmospheric correction than does the Coastal Zone Color Scanner (CZCS), if one is to utilize fully their increased radiometric sensitivity. Unlike the CZCS, the new instruments possess bands in the near infrared (NIR) that are solely for aiding atmospheric correction. We show, using aerosol models, that certain assumptions regarding the spectral behavior of the aerosol reflectance employed in the standard CZCS correction algorithm are not valid over the spectral range encompassing both the visible and the NIR. Furthermore, we show that multiple-scattering effects on the algorithm depend significantly on the aerosol model. Following these observations, we propose an algorithm that utilizes the NIR bands for atmospheric correction to the required accuracy. Examples of the dependence of the error on the aerosol model, the turbidity of the atmosphere, and surface roughness (waves) are provided. The error in the retrieved phytoplankton-pigment concentration (the principal product of ocean-color sensors) induced by errors in the atmospheric correction are shown to be <20% in approximately 90% of the cases examined. Finally, the aerosol thickness (τ(α)) is estimated through a simple extension of the correction algorithm. Simulations suggest that the error in the recovered value of τ(α) should be ≲ 10%.

A semianalytical radiance model is developed which predicts the upwelled spectral radiance at the sea surface as a function of the phytoplankton pigment concentration for Morel Case 1 waters. The model is in good agreement with experimental measurements carried out in waters which were not included in the data base used to derive it. It suggests that the observed variability in the radiance is due to variations in the backscattering of plankton and the associated detrital material. The model is extended to include other material in the water, such as dissolved organic material, referred to as yellow substances, and detached coccoliths from coccolithophorids, e.g., Emiliana huxleyi. Potential applications include an improved bio‐optical algorithm for the retrieval of pigment concentrations from satellite imagery in the presence of interference from detached coccoliths and an improved atmospheric correction for satellite imagery. The model also serves to identify and to interpret deviations from Case 1 waters.

No abstract

No abstract

Abstract.Sensors that can be used for the observation of ocean color in NASA's EarthObserving System era (SeaWiFS, MODIS, and MISR) have been designed with 2-4 times the radiometric sensitivity of the proof-of-concept ocean color instrument CZCS (coastal zone color scanner). To realize an improvement in the retrieval of biologically important ocean parameters, e.g., the concentration of the photosynthetic pigment chlorophyll a, from this increased sensitivity, significantly better atmospheric correction than was applied to CZCS is required. Atmospheric correction improvement necessitates the inclusion of the effects of multiple scattering, which are strongly dependent on the aerosol size distribution, concentration, and absorption properties. We review the basic concepts of atmospheric correction over the oceans and provide the details of the algorithms currently being developed for SeaWiFS, MODIS, and MISR. An alternate correction algorithm that could be of significant value in the coastal zone is described for MISR. Related issues such as the influence of aerosol vertical structure in the troposphere, polarization of the light field, sea surface roughness, and oceanic whitecaps on the sea surface are evaluated and plans for their inclusion in the algorithm are described. Unresolved issues, such as the presence of stratospheric aerosol, the appropriateness of the aerosol models used in the assessment of multiple scattering, and the identification of, and difficulties associated with the correction for, the presence of absorbing aerosols, e.g., urban pollution or mineral dust, are identified, and suggestions are provided for their resolution.