We present an EPR study of two Gd(III) complexes in aqueous solution at multiple temperatures and EPR frequencies. These two complexes, [Gd(TPATCN)] and [Gd(DOTAM)(H(2)O)](3+), display remarkably sharp lines (i.e. slow transverse electron spin relaxation) in comparison with all complexes studied in the past, especially at X-band ( approximately 9.08 GHz). These unprecedented spectra even show, for the first time in solution, a distinct influence of hyperfine coupling to two magnetically active Gd isotopes ((155)Gd 14.8%, I = 3/2, gamma = -0.8273 x 10(7) s(-1) T(-1) and (157)Gd, 15.65%, I = 3/2, -1.0792 x 10(7) s(-1) T(-1)). The hyperfine coupling splitting in [Gd(TPATCN)] was determined accurately for a (157)Gd-enriched complex, and the value A((157)Gd)/gmu(B) = 5.67 G seems to be a good estimation for most chelates of interest. Consequently, we can safely assert that neglecting the Gd isotopes in line shape studies is not a significant source of error as long as the apparent peak-to-peak width is greater than 10-20 G. This is generally the case, except at very high EPR frequencies (>150 GHz). Analyzing the spectra within the physical model of Rast et al. we find that the slow electron spin relaxation is due to a nearly zero static ZFS. We discuss some structural features that might explain this interesting electron structure.
We report on the generation of a nonuniform spatial distribution of the heavy and light-hole excitons in a multiple quantum wells system integrated with a localized inhomogeneous weak magnetic field. An inhomogeneous spatially resolved depression of the Zeeman splittings of the heavy-hole excitons and the light-hole excitons with respect to their translational wave vectors is observed. A localized inverted concentration of the two types of the excitons due to the inhomogeneity of the magnetic field is also measured. A simple method to integrate permanent magnetic materials with the multiple quantum wells system is used to create an accessible degree of control for magnetically manipulating the excitonic distributions.
We study with lattice techniques the localisation of gauge fields on domain wall defects in 2+1 dimensions, following a scenario originally proposed by Dvali and Shifman for 3+1 dimensions, based on confining dynamics in the bulk. We find that a localised gauge zero-mode does exist, if the domain wall is wide enough compared with the confinement scale in the bulk. The range of applicability of the corresponding low-energy effective theory is determined by the mass gap to the higher modes. For a wide domain wall, this mass gap is set by "Kaluza-Klein modes" as determined by the width. It is pointed out that in this regime the dynamical energy scales generated by the interactions of the localised zero-modes are in fact higher than the mass gap. Therefore, at least in 2+1 dimensions, the zero-modes alone do not form a low-energy effective gauge theory of a traditional type. Finally, we discuss how the situation is expected to change in going to 3+1 dimensions.
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